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Key Documents

110906

Sigma-Aldrich

trans-3-Hexene

96%

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About This Item

Linear Formula:
C2H5CH=CHC2H5
CAS Number:
Molecular Weight:
84.16
Beilstein:
1718859
EC Number:
MDL number:
UNSPSC Code:
12352100

Assay

96%

refractive index

n20/D 1.394 (lit.)

bp

67 °C (lit.)

density

0.677 g/mL at 25 °C (lit.)

SMILES string

CC\C=C\CC

InChI

1S/C6H12/c1-3-5-6-4-2/h5-6H,3-4H2,1-2H3/b6-5+

InChI key

ZQDPJFUHLCOCRG-AATRIKPKSA-N

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Application

trans-3-Hexene has been used to study the asymmetric catalytic epoxidation of various unfunctionalized alkenes using C2-symmetrical, 1,1′-binaphthyl-2,2′-dimethylene-bridged ansa-Bis(1-indenyl)titanium dichloride complex as the catalyst.

Other Notes

Contains trans-2-hexene

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Asymmetric epoxidation of unfunctionalized alkenes using the new C2-symmetrical 1,1′-binaphthyl-2,2′-dimethylene-bridged ansa-Bis(1-indenyl)titanium dichloride catalyst.
Tetrahedron Letters, 33(8), 1005-1100 (1992)

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