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154903

Sigma-Aldrich

Methanol

≥99.9%, ACS spectrophotometric grade, suitable for UV/Vis spectroscopy

Synonym(s):

Methyl alcohol

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About This Item

Linear Formula:
CH3OH
CAS Number:
Molecular Weight:
32.04
Beilstein:
1098229
EC Number:
MDL number:
UNSPSC Code:
12352104
eCl@ss:
39020101
PubChem Substance ID:
NACRES:
NA.21

product name

Methanol, ACS spectrophotometric grade, ≥99.9%

grade

ACS spectrophotometric grade

Quality Level

vapor density

1.11 (vs air)

vapor pressure

410 mmHg ( 50 °C)
97.68 mmHg ( 20 °C)

Assay

≥99.9%

form

liquid

autoignition temp.

725 °F

expl. lim.

36 %

technique(s)

UV/Vis spectroscopy: suitable

impurities

MnO4- reducers, passes test
≤0.0002 meq/g Titr. base
≤0.0003 meq/g Titr. acid
≤0.001% acetaldehyde
≤0.001% acetone
≤0.001% formaldehyde
≤0.1% water

evapn. residue

≤0.001%

color

APHA: ≤10
clear

refractive index

n20/D 1.329 (lit.)

bp

64.7 °C (lit.)

mp

−98 °C (lit.)

density

0.791 g/mL at 25 °C (lit.)

λ

H2O reference

UV absorption

λ: 205 nm Amax: 1.00
λ: 210 nm Amax: 0.80
λ: 220 nm Amax: 0.40
λ: 230 nm Amax: 0.20
λ: 240 nm Amax: 0.10
λ: 260 nm Amax: 0.04
λ: 280-400 nm Amax: 0.01

application(s)

food and beverages

format

neat

storage temp.

room temp

SMILES string

CO

InChI

1S/CH4O/c1-2/h2H,1H3

InChI key

OKKJLVBELUTLKV-UHFFFAOYSA-N

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General description

Thermochemical conversion of methanol to C2-C10 hydrocarbons in the presence of shape-selective zeolites has been reported. Its oxidation on Ru-Pt catalyst system by ruthenium ad-atoms has been proposed.

Application

Used as a solvent in:
  • Preparation of self-assembled monolayers (SAMs) of sulfur derivatives with bactericidal terminal fragments on gold surfaces prior to analytical characterization
  • Measurement of soluble absorption spectra of PTFE samples

Preparation Note

Product filtered through a 0.2 μm filter

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

Target Organs

Eyes,Central nervous system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

49.5 °F - closed cup

Flash Point(C)

9.7 °C - closed cup


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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The conversion of methanol and other O-compounds to hydrocarbons over zeolite catalysts.
Chang CD and Silvestri AJ.
J. Catal., 47(2), 249-259 (1977)
Electrocatalysis by ad-atoms: Part II. Enhancement of the oxidation of methanol on platinum by ruthenium ad-atoms.
Watanabe MA and Motoo S.
J. Electroanal. Chem. Interfac. Electrochem., 60(3), 267-273 (1975)
B Alkhatib et al.
European cells & materials, 28, 98-110 (2014-09-13)
Excessive mechanical loading or acute trauma to intervertebral discs (IVDs) is thought to contribute to degeneration and pain. However, the exact mechanisms by which mechanical injury initiates and promotes degeneration remain unclear. This study investigates biochemical changes and extracellular matrix
Timo Heidt et al.
Circulation research, 115(2), 284-295 (2014-05-03)
Macrophages populate the steady-state myocardium. Previously, all macrophages were thought to arise from monocytes; however, it emerged that, in several organs, tissue-resident macrophages may self-maintain through local proliferation. Our aim was to study the contribution of monocytes to cardiac-resident macrophages
Nicolas Vodovar et al.
European heart journal, 35(48), 3434-3441 (2014-08-27)
Increases in plasma B-type natriuretic peptide (BNP) concentrations in those with acutely decompensated heart failure (ADHF) has been mainly attributed to an increase in NPPB gene transcription. Recently, proBNP glycosylation has emerged as a potential regulatory mechanism in the production

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