T8258
Trifluoroacetic anhydride
liquid
Synonym(s):
TFAA
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About This Item
Linear Formula:
(CF3CO)2O
CAS Number:
Molecular Weight:
210.03
Beilstein:
746197
EC Number:
MDL number:
UNSPSC Code:
12352100
Recommended Products
vapor pressure
6.28 psi ( 20 °C)
form
liquid
color
clear colorless
refractive index
n20/D 1.3 (lit.)
bp
39.5-40 °C (lit.)
mp
−65 °C (lit.)
density
1.511 g/mL at 20 °C (lit.)
SMILES string
FC(F)(F)C(=O)OC(=O)C(F)(F)F
InChI
1S/C4F6O3/c5-3(6,7)1(11)13-2(12)4(8,9)10
InChI key
QAEDZJGFFMLHHQ-UHFFFAOYSA-N
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Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1A
Supplementary Hazards
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 2
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Angelos Halaris et al.
Journal of psychiatric research, 66-67, 118-126 (2015-05-27)
A pro-inflammatory state and a dysregulation in the tryptophan/kynurenine pathway have been documented in depression. This study examined whether treatment with the SSRI, escitalopram (ESC), could suppress inflammation and favorably shift metabolites of the kynurenine pathway in patients with major
Hidenori Kinoshita et al.
Journal of the American Chemical Society, 132(18), 6412-6418 (2010-04-17)
Reaction screening of nucleophilic reaction partners for addition to N-diphenylphosphinylimines employing lanthanum(III) triflate as a catalyst and trifluoroacetic anhydride (TFAA) as an activator is reported. A number of tandem processes leading to novel chemotypes including aza-Prins/intramolecular Friedel-Crafts annulations have been
Philippe Nuhant et al.
The Journal of organic chemistry, 74(24), 9413-9421 (2009-11-21)
Aminopentadienals resulting from the condensation of tryptamine or homoveratrylamine with glutaconaldehydes were treated with trifluoroacetic anhydride, allowing the formation of tetrahydro-beta-carbolines and tetrahydroisoquinolines bearing an enal function. In this N-acyl Pictet-Spengler reaction the electrophilicity of the aminopentadienals was dramatically increased
Bjorn J A Berendsen et al.
Analytica chimica acta, 585(1), 126-133 (2007-03-28)
Derivatisation of the avermectines ivermectin (IVM), doramectin (DOR), abamectin (ABA) and eprinomectin (EPR), and the milbemycin moxidectin (MOX) to fluorescent derivatives is commonly used for quantitative analysis at relevant levels using high performance liquid chromatography (HPLC) with fluorescence detection. Problems
H Christine Lo et al.
Journal of the American Chemical Society, 129(5), 1246-1253 (2007-02-01)
Re(2)O(7), which is known primarily as a strong oxidant, was found to be a highly selective Lewis acid catalyst that affects the heteroacylative dimerization of THF at room temperature. This multicomponent reaction, which involves THF, trifluoroacetic anhydride (TFAA), and a
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