91746
Triisopropylsilyl trifluoromethanesulfonate
purum, ≥98.0% (T)
Synonym(s):
TIPS triflate, Trifluoromethanesulfonic acid triisopropylsilyl ester, Triisopropylsilyl triflate
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About This Item
Linear Formula:
CF3SO3Si[CH(CH3)2]3
CAS Number:
Molecular Weight:
306.42
Beilstein:
3591541
MDL number:
UNSPSC Code:
12352000
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grade
purum
Assay
≥98.0% (T)
refractive index
n20/D 1.415 (lit.)
bp
45-46 °C/0.03 mmHg
density
1.14 g/mL at 25 °C (lit.)
SMILES string
CC(C)[Si](OS(=O)(=O)C(F)(F)F)(C(C)C)C(C)C
InChI
1S/C10H21F3O3SSi/c1-7(2)18(8(3)4,9(5)6)16-17(14,15)10(11,12)13/h7-9H,1-6H3
InChI key
LHJCZOXMCGQVDQ-UHFFFAOYSA-N
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Other Notes
Reagent for the smooth introduction of the TIPS group; Review
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Find documentation for the products that you have recently purchased in the Document Library.
G. Simchen
Advances in Silicon Chemistry, 1, 189-189 null
E.J. Corey et al.
Tetrahedron Letters, 25, 4345-4345 (1984)
E.J. Corey et al.
Tetrahedron Letters, 22, 3455-3455 (1981)
J.M. Muchowski et al.
Tetrahedron Letters, 26, 5375-5375 (1985)
R. Bruckmann et al.
Chemische Berichte, 120, 635-635 (1987)
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