72800
4-Nitrobenzaldehyde
for spectrophotometric det. of amino sugars, ≥99.0%
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About This Item
Linear Formula:
O2NC6H4CHO
CAS Number:
Molecular Weight:
151.12
Beilstein:
386796
EC Number:
MDL number:
UNSPSC Code:
12000000
PubChem Substance ID:
NACRES:
NA.21
Recommended Products
Quality Level
Assay
≥99.0% (HPLC)
≥99.0%
form
powder
quality
for spectrophotometric det. of amino sugars
technique(s)
UV/Vis spectroscopy: suitable
ign. residue
≤0.05%
mp
103-106 °C (lit.)
104-106 °C
SMILES string
[O-][N+](=O)c1ccc(C=O)cc1
InChI
1S/C7H5NO3/c9-5-6-1-3-7(4-2-6)8(10)11/h1-5H
InChI key
BXRFQSNOROATLV-UHFFFAOYSA-N
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Other Notes
Reagent for the spectrophotometric det. of amino carbohydrates
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Sens. 1
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Several proteases, especially pepsin, were observed to directly catalyze asymmetric aldol reactions. Pepsin, which displays well-documented proteolytic activity under acidic conditions, exhibited distinct catalytic activity in a crossed aldol reaction between acetone and 4-nitrobenzaldehyde with high yield and moderate enantioselectivity.
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Condensation of 3-aminocoumarin (5) with 4-nitrobenzaldehyde (8) afforded a 2-azadiene (9), which reacted with various electron-rich alkenes (10 examples) in the presence of Yb(OTf)3 to afford 1,2,3,4-tetrahydropyrido[2,3-c]coumarins. Yields were generally good, but the diastereomeric ratios were highly variable. The products
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