18105
3-Bromo-1,2-propanediol
technical, ≥96% (GC)
Synonym(s):
α-Glycerol bromohydrin
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About This Item
Linear Formula:
CH2BrCHOHCH2OH
CAS Number:
Molecular Weight:
154.99
Beilstein:
1719124
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
Recommended Products
grade
technical
Assay
≥96% (GC)
refractive index
n20/D 1.518 (lit.)
n20/D 1.518
bp
72-75 °C/0.2 mmHg (lit.)
density
1.771 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
OCC(O)CBr
InChI
1S/C3H7BrO2/c4-1-3(6)2-5/h3,5-6H,1-2H2
InChI key
SIBFQOUHOCRXDL-UHFFFAOYSA-N
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Other Notes
Protecting group reagent for carbonyl functions.; The bromomethylethylene ketals can be cleaved under neutral conditions
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
235.4 °F - closed cup
Flash Point(C)
113 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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A R Jones et al.
Journal of applied toxicology : JAT, 16(1), 57-63 (1996-01-01)
(R,S)- and (R)-3-Bromopropan-1,2-diol (alpha-bromohydrin) produced diuresis and glucosuria when administered to male rats but had no effect on the metabolic activity of rat kidney tubules in vitro. The oxidation products (R,S)-3-bromolactate and 3-bromopyruvate produced brief phases of diuresis but not
E.J. Corey et al.
The Journal of Organic Chemistry, 38, 834-834 (1973)
A R Jones et al.
Journal of reproduction and fertility, 108(1), 95-100 (1996-09-01)
Boar spermatozoa incubated with glycerol 3-phosphate as substrate produced CO2 and an accumulation of dihydroxyacetone phosphate and fructose-1,6-bisphosphate. The rate of oxidation of glycerol 3-phosphate was decreased, as was the production of CO2 and the two glycolytic intermediates, in the
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