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723223

Sigma-Aldrich

Dodecyl 2-bromoisobutyrate

Synonym(s):

Dodecyl initiator

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About This Item

Empirical Formula (Hill Notation):
C16H31BrO2
CAS Number:
934001-46-4
Molecular Weight:
335.32
MDL number:
MFCD16621497
UNSPSC Code:
12162002
PubChem Substance ID:
329763988

form

liquid

refractive index

n20/D 1.455

density

1.058 g/mL at 25 °C

SMILES string

CCCCCCCCCCCCOC(=O)C(C)(C)Br

InChI

1S/C16H31BrO2/c1-4-5-6-7-8-9-10-11-12-13-14-19-15(18)16(2,3)17/h4-14H2,1-3H3

InChI key

TUPZPNIRCIQNLF-UHFFFAOYSA-N

Application

Atom Transfer Radical Polymerization (ATRP) initiator for the creation of dodecyl functionalized telechelic polymers.

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302,H315,H318,H335

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Coessens, V.; Pintauer, T.; Matyjaszewski, K.
Progress in Polymer Science, 26, 337-337 (2001)
Atom transfer radical polymerization.
K Matyjaszewski et al.
Chemical reviews, 101(9), 2921-2990 (2001-12-26)
"Green" atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials.
Nicolay V Tsarevsky et al.
Chemical reviews, 107(6), 2270-2299 (2007-05-29)

Articles

ATRP Ligands & Initiators: Clean Functional Polymers

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

Protocols

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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