717452

Tris(triphenylsiloxy)vanadium oxide

95%

• Synonym(s): NSC 349960, Oxotris(triphenylsilanolato) vanadium, Triphenylsilanol vanadate
• Empirical Formula (Hill Notation): C₅₄H₄₅O₄Si₃V
• CAS Number: 18822-50-9
• Molecular Weight: 893.13
• MDL number: MFCD00301697
• UNSPSC Code: 12352300
• PubChem Substance ID: 329763491

Properties

• Assay: 95%
• form: powder
• reaction suitability: core: vanadium; reagent type: catalyst
• mp: 224-226 °C
• SMILES string: O=[V](O[Si](c1ccccc1)(c2ccccc2)c3ccccc3)(O[Si](c4ccccc4)(c5ccccc5)c6ccccc6)O[Si](c7ccccc7)(c8ccccc8)c9ccccc9
• InChI: 1S/3C18H15OSi.O.V/c3*19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;;/q3*-1;;+3
• InChI key: WSQFWIWHGOUAEN-UHFFFAOYSA-N

Description

Application

Catalyst for:

• Dual catalyst system for Meyer-Schuster rearrangement
• Esterification
• Addition of propargyl alcohols and imines or aldehydes
• Photochemical polymerization of Me methacylate

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable