482099
Cyclopropanemethanol
≥99.5%
Synonym(s):
(Hydroxymethyl)cyclopropane, CPMO, Cyclopropyl carbinol, Cyclopropylmethanol
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25 ML
₪576.00
250 ML
₪1,594.00
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₪3,183.00
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25 ML
₪576.00
250 ML
₪1,594.00
1 L
₪3,183.00
About This Item
Linear Formula:
C3H5CH2OH
CAS Number:
Molecular Weight:
72.11
Beilstein:
1846846
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Quality Level
Assay
≥99.5%
refractive index
n20/D 1.431 (lit.)
bp
123-124 °C/738 mmHg (lit.)
density
0.89 g/mL at 25 °C (lit.)
functional group
hydroxyl
SMILES string
OCC1CC1
InChI
1S/C4H8O/c5-3-4-1-2-4/h4-5H,1-3H2
InChI key
GUDMZGLFZNLYEY-UHFFFAOYSA-N
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General description
Cyclopropanemethanol (Cyclopropyl carbinol, CPMO), a cycloalkanemethanol, is an anaesthetic.[1] The coupling reaction of cyclopropanemethanol with alkynes to form substituted allylic alcohols has been reported.[2] The microwave spectrum of CPMO has been recorded. Its rotational constants and dipole moment have been determined.[3]
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Liq. 3
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point(F)
95.0 °F - closed cup
Flash Point(C)
35 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Surbhi Soni et al.
Chirality, 30(1), 85-94 (2017-10-25)
A profoundly time-efficient chemoenzymatic method for the synthesis of (S)-3-(4-chlorophenoxy)propan-1,2-diol and (S)-1-chloro-3-(2,5-dichlorophenoxy)propan-2-ol, two important pharmaceutical intermediates, was successfully developed using Pseudomonas fluorescens lipase (PFL). Kinetic resolution was successfully achieved using vinyl acetate as acylating agent, toluene/hexane as solvent, and reaction
D E Raines et al.
Anesthesiology, 78(5), 918-927 (1993-05-01)
N-alkanols containing up to 12 carbons are anesthetic; however, those with more than 12 carbons are not. This phenomenon has been termed cutoff. Lipid disordering theories of anesthesia suggest that cutoff occurs because the alkyl chains of long-chain alcohols approach
Cyclopropylmethyl dihydrogen phosphate. Preparation and use in the phosphorylation of nucleosides.
Schoffstall AM.
The Journal of Organic Chemistry, 40(23), 3444-3445 (1975)
Galvanic Deposition of Au on Paperlike Cu Fiber for High-Efficiency, Low-Temperature Gas-Phase Oxidation of Alcohols.
Zhao G, et al.
ChemCatChem, 3(10), 1629-1636 (2011)
Nickel-Catalyzed Redox-Economical Coupling of Alcohols and Alkynes to Form Allylic Alcohols.
Nakai K, et al.
Journal of the American Chemical Society, 136(22), 7797-7800 (2014)
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