399949
Vanadium(V) oxyfluoride
99%
Synonym(s):
Vanadium(V) oxytrifluoride, Vanadyl trifluoride
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About This Item
Linear Formula:
VOF3
CAS Number:
Molecular Weight:
123.94
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
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Quality Level
Assay
99%
form
powder
reaction suitability
reagent type: catalyst
core: vanadium
solubility
H2O: insoluble(lit.)
application(s)
battery manufacturing
SMILES string
F[V](F)(F)=O
InChI
1S/3FH.O.V/h3*1H;;/q;;;;+3/p-3
InChI key
FXGIDXZUDLFPLD-UHFFFAOYSA-K
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Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
Supplementary Hazards
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Micah J Niphakis et al.
Organic letters, 13(2), 196-199 (2010-12-15)
A highly convergent strategy to prepare phenanthroindolizidines is reported involving three consecutive C-C coupling reactions. This sequence features a novel VOF(3)-mediated aryl-alkene coupling in the final step, which enables regioselective preparation of C5-substituted phenanthroindolizidines for the first time. This strategy
M D Zidan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 56(14), 2693-2698 (2001-01-06)
A new route has been devised, leading to the production of VOX3 molecules where X=F, Br and I by an on-line process using vanadium oxytrichloride, VOCl3 as a starting compound passed over the following heated salts NaF, KBr and KI
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