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357499

Sigma-Aldrich

Tin(IV) chloride solution

1.0 M in heptane

Synonym(s):

Stannic chloride, Tin tetrachloride

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About This Item

Linear Formula:
SnCl4
CAS Number:
7646-78-8
Molecular Weight:
260.52
MDL number:
MFCD00011242
UNSPSC Code:
12352106
PubChem Substance ID:
24861921
NACRES:
NA.22

form

liquid

reaction suitability

core: tin
reagent type: Lewis acid
reagent type: catalyst

concentration

1.0 M in heptane

density

0.874 g/mL at 25 °C

SMILES string

Cl[Sn](Cl)(Cl)Cl

InChI

1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4

InChI key

HPGGPRDJHPYFRM-UHFFFAOYSA-J

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Signal Word

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

24.8 °F - closed cup

Flash Point(C)

-4.0 °C - closed cup

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Certificates of Analysis (COA)

Lot/Batch Number
SHBN1813
SHBJ0636
SHBD2928V
SHBC2446
18496TM

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Gerry A Griffith et al.
Journal of the American Chemical Society, 128(40), 13130-13141 (2006-10-05)
Difluorinated alkenoate ethyl 3,3-difluoro-2-(N,N-diethylcarbamoyloxy)-2-propenoate reacts rapidly and in high yield with furan and a range of substituted furans in the presence of a tin(IV) catalyst. Non-fluorinated congener 2-(N,N-diethylcarbamoyloxy)-2-propenoate fails to react at all under the same conditions. These reactions have
Yasuyuki Kita et al.
The Journal of organic chemistry, 71(14), 5191-5197 (2006-07-01)
The Lewis acid-promoted rearrangement of 2,2,3,3-tetrasubstituted 2,3-epoxy alcohols with several kinds of protecting groups was investigated. When SnCl4 is used as a Lewis acid, the reaction proceeds in a regio- and stereo-controlled manner to afford two types of carbonyl compounds
Leo A Paquette et al.
The Journal of organic chemistry, 68(22), 8614-8624 (2003-10-25)
The concept of spirocyclic restriction, when generically applied to nucleoside mimics, allows for the preparation of diastereomeric pairs carrying either a syn- or anti-oriented hydroxyl at C-5'. Reported herein are convenient synthetic routes to enantiomerically pure 1-oxaspiro[4.4]nonanes featuring fully dihydroxylated
L Malaguarnera et al.
Journal of cellular biochemistry, 93(1), 197-206 (2004-09-08)
The pituitary hormone prolactin (PRL) is a multifunctional polypeptide which exerts a role on cell proliferation and may also contribute to cell differentiation. PRL is also produced by immune cells and is regarded as a key component of the neuroendocrine-immune
Colin O'Brien et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 13(3), 902-909 (2006-11-07)
The reaction of silylated nucleophiles with 6,1-anhydroglucopyranuronic acid (glucuronic acid 6,1-lactones) catalysed by tin(IV) chloride provides 1,2-trans or 1,2-cis (deoxy)glycosides in a manner dependent on the donor structure. The alpha-glycoside was obtained for reactions of the donor with the 2-acyl
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