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335150

Sigma-Aldrich

Phenylsilane

97%

Synonym(s):

Monophenylsilane

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1 G
₪159.00
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₪520.00
25 G
₪1,584.00
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₪21,603.00

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1 G
₪159.00
5 G
₪520.00
25 G
₪1,584.00
500 G
₪21,603.00

About This Item

Linear Formula:
C6H5SiH3
CAS Number:
694-53-1
Molecular Weight:
108.21
Beilstein:
2935169
EC Number:
211-772-5
MDL number:
MFCD00013478
UNSPSC Code:
12352103
PubChem Substance ID:
24860291
NACRES:
NA.22

₪159.00

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Quality Level

100

Assay

97%

form

liquid

refractive index

n20/D 1.510 (lit.)

bp

120 °C (lit.)

density

0.877 g/mL at 25 °C (lit.)

SMILES string

[SiH3]c1ccccc1

InChI

1S/C6H8Si/c7-6-4-2-1-3-5-6/h1-5H,7H3

InChI key

PARWUHTVGZSQPD-UHFFFAOYSA-N

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Application

Phenylsilane (PhSiH3) may be used as a reducing agent for the partial reduction of phosphine oxide groups in poly(4,4′-diphenylphenylphosphine oxide) (PAPO) to phosphine.[1] It can also undergo photopolymerization with methyl methacrylate(MMA) to form poly(MMA) containing SiH groups.[2] PhSiH3 may be used as a silicon source to synthesize crystalline Si nanowires via Au-nanocrystal-seeded supercritical fluid-liquid-solid (SFLS) synthesis.[3]

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 1

Flash Point(F)

46.4 °F - closed cup

Flash Point(C)

8 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW3777
SHBR6109
SHBN4943
SHBH2620V
SHBH0006V

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Xiaoyan Yin et al.
Colloids and surfaces. B, Biointerfaces, 195, 111271-111271 (2020-08-01)
Lipidated peptide amphiphiles exhibit high affinity for plasma cell membranes, good cell internalization and improved stability against degradation, which make them attractive as a drug delivery system. However, low drug loading capacity limits their application for drug delivery. Herein, we
Tadhg Kennedy et al.
ACS nano, 9(7), 7456-7465 (2015-07-01)
Here we report the rational design of a high-capacity Li-ion anode material comprising Ge nanowires with Si branches. The unique structure provides an electrode material with tunable properties, allowing the performance to be tailored for either high capacity or high
Photopolymerization of Methyl methacrylate with Phenylsilane.
Hong L-Y
Bull. Korean Chem. Soc., 16(4), 360-363 (1995)
Synthesis of poly (arylene phosphine oxide) by nickel-catalysed coupling polymerization.
Ghassemi H
Polymer, 38(12), 3139-3143 (1997)
Chayanon Ngambenjawong et al.
Bioconjugate chemistry, 27(12), 2854-2862 (2016-10-26)
Peptide cyclization is a strategy used to improve stability and activity of peptides. The most commonly used cyclization method is disulfide bridge formation of cysteine-containing peptides, as is typically found in nature. Over the years, an increasing number of alternative
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Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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