Skip to Content
Merck
All Photos(2)

Documents

260053

Sigma-Aldrich

2-Bromo-6-nitrotoluene

98%

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
CH3C6H3(NO2)Br
CAS Number:
55289-35-5
Molecular Weight:
216.03
Beilstein:
2502581
EC Number:
259-566-4
MDL number:
MFCD00009792
UNSPSC Code:
12352100
PubChem Substance ID:
24855451
NACRES:
NA.22

Assay

98%

form

solid

bp

143 °C/22 mmHg (lit.)

mp

38-40 °C (lit.)

SMILES string

Cc1c(Br)cccc1[N+]([O-])=O

InChI

1S/C7H6BrNO2/c1-5-6(8)3-2-4-7(5)9(10)11/h2-4H,1H3

InChI key

LYTNSGFSAXWBCA-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Application

2-Bromo-6-nitrotoluene has been used:
  • as starting reagent in total synthesis of N-acetyl methyl ester of (±)-clavicipitic acids
  • in synthesis of carbazomadurin A, highly oxygenated neuronal cell protecting carbazole alkaloid

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Palladium-catalyzed reactions in the synthesis of 3-and 4-substituted indoles. 2. Total synthesis of the N-acetyl methyl ester of (?)-clavicipitic acids.
Harrington PJ, et al.
Journal of the American Chemical Society, 109(14), 4335-4338 (1987)
Hans-Joachim Knölker et al.
Chemical communications (Cambridge, England), (10)(10), 1170-1171 (2003-06-05)
The highly oxygenated neuronal cell protecting carbazole alkaloid carbazomadurin A was synthesized in nine steps and 11% overall yield from isovanillic acid.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service