178969
Tri-sec-butylborane solution
1.0 M in THF
Synonym(s):
Tris(1-methylpropyl)borane
About This Item
Quality Level
reaction suitability
reagent type: reductant
concentration
1.0 M in THF
density
0.799 g/mL at 25 °C
SMILES string
CCC(C)B(C(C)CC)C(C)CC
InChI
1S/C12H27B/c1-7-10(4)13(11(5)8-2)12(6)9-3/h10-12H,7-9H2,1-6H3
InChI key
YUPAWYWJNZDARM-UHFFFAOYSA-N
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Application
- Allylic alkylations for synthesis of unsaturated aldehydes and alcohols
- Cis-addition of carbon-hydrogen bonds of pyrroles and thiophenes to alkynes
- Borane-induced radical reduction of alkenyl and alkynyliodanes
- Initiating polymerization for synthesis of polymethylenes and ethylene-propylene
- Asymmetric synthesis of vinylglycidols
- Asymmetric addition of alcohols to vinyl epoxides
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point(F)
1.4 °F
Flash Point(C)
-17 °C
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