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83694

Sigma-Aldrich

Rhodamine 101 inner salt

for fluorescence

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About This Item

Empirical Formula (Hill Notation):
C32H30N2O3
CAS Number:
116450-56-7
Molecular Weight:
490.59
Beilstein:
5680006
MDL number:
MFCD00210089
UNSPSC Code:
12171500
PubChem Substance ID:
57652963
NACRES:
NA.32

grade

for fluorescence

form

solid

solubility

methanol: soluble

fluorescence

λex 560 nm; λem 589 nm in methanol

SMILES string

[O-]C(=O)c1ccccc1C2=C3C=C4CCC[N+]5=C4C(CCC5)=C3Oc6c7CCCN8CCCc(cc26)c78

InChI

1S/C32H30N2O3/c35-32(36)22-10-2-1-9-21(22)27-25-17-19-7-3-13-33-15-5-11-23(28(19)33)30(25)37-31-24-12-6-16-34-14-4-8-20(29(24)34)18-26(27)31/h1-2,9-10,17-18H,3-8,11-16H2

InChI key

MUSLHCJRTRQOSP-UHFFFAOYSA-N

Related Categories

General description

Rhodamine 101 (Rh101) is a highly stable fluorophore in the rhodamine family.

Application

Rhodamine 101 (Rh101, compound 1) has been used:
  • as a reference model for analysing extra fluorochromic properties of rhodamine derivatives
  • as a reference against thioflavin t (ThT) in the determination of ensemble photophysical properties
  • as reference compound for comparing the quantum yields of nanocrystals

Biochem/physiol Actions

Rhodamine 101 (Rh101) is useful as a reference material to measure the fluorescence quantum yield.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Ryota Iwai et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology (2020-05-21)
Diarylethene derivatives having benzothiophene S,S-dioxide groups undergo turn-on mode fluorescence photoswitching. For the practical application to super-resolution fluorescence microscopy, photoswitchable fluorescent molecules are desired to be resistant against photodegradation. Here we synthesized turn-on mode fluorescent diarylethenes having electron-withdrawing (trifluoromethyl or
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Royal Society open science, 5(2), 171399-171399 (2018)
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Inorganic Chemistry, 55(17), 8381-8386 (2016)
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