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236497

Sigma-Aldrich

Potassium acetate

ACS reagent, ≥99.0%

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100 G
€48.80
500 G
€157.00
2.5 KG
€636.00

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100 G
€48.80
500 G
€157.00
2.5 KG
€636.00

About This Item

Linear Formula:
CH3COOK
CAS Number:
Molecular Weight:
98.14
Beilstein:
3595449
EC Number:
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.21
Assay:
≥99.0%
grade:
ACS reagent
form:
powder or crystals
solubility:
water: soluble 98.2 g/L at 20 °C

€48.80


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grade

ACS reagent

Quality Level

vapor pressure

<0.0000001 hPa ( 25 °C)

Assay

≥99.0%

form

powder or crystals

impurities

≤0.005% insolubles

pH

6.5-9.0 (25 °C, 5%)

solubility

water: soluble 98.2 g/L at 20 °C

density

1.57 g/cm3 at 25 °C (lit.)

anion traces

chloride (Cl-): ≤0.003%
phosphate (PO43-): ≤0.001%
sulfate (SO42-): ≤0.002%

cation traces

Ca: ≤0.005%
Fe: ≤5 ppm
Mg: ≤0.002%
Na: ≤0.03%
heavy metals: ≤5 ppm (as Pb)

suitability

complies for IR spectroscopy

SMILES string

[K+].CC([O-])=O

InChI

1S/C2H4O2.K/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1

InChI key

SCVFZCLFOSHCOH-UHFFFAOYSA-M

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General description

Potassium acetate is a hygroscopic material used as a base in organic synthesis. It can also be used as a buffer and neutralizing agent.

Application

Potassium acetate can be used:
  • As a catalyst in the glycolysis of rigid polyurethane (PU) using DEG (diethylene glycol) as a solvent.
  • As a nucleophilic catalyst for addition and polymerization reaction.
  • As a nucleophilic catalyst in the regioselective reaction of epoxides with S-phenyl thioesters.
  • As a promoter/base in transition metal-catalyzed reactions.
  • As a source of methyl radical in photo-decarboxylative nucleophilic additions to phthalimides and source of potassium ion for templating reactions.

Potassium acetate can also be used as a base:
  • In the Lossen rearrangement of hydroxamic acid.
  • In the E2 elimination′s reaction.
  • In the fragmentation of α,α-dichloroketoesters and deprotonation of alcohols.

Legal Information

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Potassium acetate-catalyzed acetylation of wood: extraordinarily rapid acetylation at 120 C.
Obataya E and Minato K.
Wood Science and Technology, 42(7), 567-577 (2008)
Eagleson M.
Concise Encyclopedia Chemistry, 886-886 (1994)
Carrie Goodson et al.
Eukaryotic cell, 10(12), 1592-1606 (2011-11-01)
Light microscopy and deep-etch electron microscopy were used to visualize triacylglyceride (TAG)-filled lipid bodies (LBs) of the green eukaryotic soil alga Chlamydomonas reinhardtii, a model organism for biodiesel production. Cells growing in nitrogen-replete media contain small cytoplasmic lipid bodies (α-cyto-LBs)
Jay D Gralla et al.
The EMBO journal, 25(7), 1515-1521 (2006-03-17)
Potassium glutamate accumulates upon hyper-osmotic shock and serves as a temporary osmoprotectant. This salt leads to transcriptional activation of sets of genes that allow the cell to achieve long-term adaptation to high osmolarity. The current experiments show that potassium glutamate
Yuval Erez et al.
The journal of physical chemistry. A, 116(9), 2039-2048 (2012-02-10)
Steady-state and time-resolved emission techniques were employed to study the effect of acetate, a mild base, on the luminescence of curcumin in methanol and ethanol. We found that the steady-state emission intensity as well as the average fluorescence decay time

Questions

1–3 of 3 Questions  
  1. what is the content in ppm of residual/ unreacted Acetic acid in Potassium Acetate .

    1 answer
    1. The amount of residual acetic acid in this material has not been determined.

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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