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21310

Sigma-Aldrich

(±)-Camphor

purum, synthetic, ≥95.0% (GC)

Synonym(s):

1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one

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50 G
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250 G
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1 KG
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About This Item

Empirical Formula (Hill Notation):
C10H16O
CAS Number:
76-22-2
Molecular Weight:
152.23
Beilstein:
1907611
EC Number:
200-945-0
MDL number:
MFCD00074738
UNSPSC Code:
12352100
PubChem Substance ID:
329752137
NACRES:
NA.22

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vapor density

5.2 (vs air)

Quality Level

200

vapor pressure

4 mmHg ( 70 °C)

grade

purum

Assay

≥95.0% (GC)

quality

synthetic

expl. lim.

3.5 %

impurities

≤0.5% water

bp

204 °C (lit.)

mp

175-177 °C (lit.)

solubility

ethanol: soluble 1 g/10 mL, clear, colorless
water: soluble

functional group

ketone

SMILES string

[H][C@](CC1=O)(CC2)C(C)(C)[C@]12C

InChI

1S/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3/t7-,10+/m1/s1

InChI key

DSSYKIVIOFKYAU-XCBNKYQSSA-N

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Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 2 Inhalation

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 1

Flash Point(F)

147.9 °F - closed cup

Flash Point(C)

64.4 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
STBL3625
STBL1283
STBK8466
STBK2791
STBK7072

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Highly diastereoselective synthesis of new optically active aminoalcohols in one step from (+)-camphor and (-)-fenchone.
Genov M, et al.
Tetrahedron Asymmetry, 8(11), 1869-1876 (1997)
Planer nano-graphenes from camphor by CVD.
Somani PR, et al.
Chemical Physics Letters, 430(1), 56-59 (2006)
Christian Merten et al.
The journal of physical chemistry. A, 116(27), 7329-7336 (2012-06-06)
In the present work, the first observation of strong resonance Raman optical activity (RROA) involving more that one resonant electronic state is reported. The chiral transition metal complex bis-(trifluoroacetylcamphorato) copper(II), abbreviated Cu(tfc)(2), exhibits both resonance Raman (RR) and RROA spectra
Shigeki Yamamoto et al.
Journal of computational chemistry, 34(25), 2152-2158 (2013-07-05)
Induced resonance Raman optical activity (IRROA) proved to be a very sensitive method to detect molecular chirality. It is exhibited, for example, by complexes of lanthanides with chiral alcohols or ketones. So far, the phenomenon has not been understood at
Dong-Bin Dang et al.
Chemical communications (Cambridge, England), 49(22), 2243-2245 (2013-02-12)
A series of 3D homochiral manganese-lanthanide frameworks have been synthesized based on chiral camphoric acid. In the heterometallic features, D-camphoric acids are unprecedentedly embedded in three coordination modes.
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Chromatograms

suitable for GC

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