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8.00889

Sigma-Aldrich

Methyl formate

for synthesis

Synonym(s):

Methyl formate, Formic acid methyl ester

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About This Item

Empirical Formula (Hill Notation):
C2H4O2
CAS Number:
Molecular Weight:
60.05
MDL number:
UNSPSC Code:
12352108
EC Index Number:
203-481-7
NACRES:
NA.22

vapor pressure

644 hPa ( 20 °C)

Quality Level

Assay

95.0-97.0% (GC)

form

liquid

autoignition temp.

450 °C

potency

1500 mg/kg LD50, oral (Rat)
>4000 mg/kg LD50, skin (Rat)

expl. lim.

5-23 % (v/v)

pH

4-5 (20 °C, 200 g/L in H2O)

bp

31.5 °C/1013 hPa

mp

-100.4 °C

transition temp

flash point -32 °C

solubility

300 g/L

density

0.968 g/cm3 at 20 °C

storage temp.

2-30°C

InChI

1S/C2H4O2/c1-4-2-3/h2H,1H3

InChI key

TZIHFWKZFHZASV-UHFFFAOYSA-N

Analysis Note

Assay (GC, area%): 95.0 - 97.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.967 - 0.971
Methanol (GC, area%): 3.0 - 5.0 % (a/a)
Identity (IR): passes test

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

-25.6 °F

Flash Point(C)

-32 °C


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH Annex XVII (Restriction List)

CAS No.

Certificates of Analysis (COA)

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