676578

Bis(tri-tert-butylphosphine)palladium(0)

• Synonym(s): Pd(t-Bu₃P)₂
• Empirical Formula (Hill Notation): C₂₄H₅₄P₂Pd
• CAS Number: 53199-31-8
• Molecular Weight: 511.05
• MDL number: MFCD03094580
• UNSPSC Code: 12161600
• PubChem Substance ID: 24884857
• NACRES: NA.22

Properties

• form: solid
• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 258-272 °C
• greener alternative category: , Aligned
• storage temp.: −20°C
• SMILES string: [Pd].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C
• InChI: 1S/2C12H27P.Pd/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;
• InChI key: MXQOYLRVSVOCQT-UHFFFAOYSA-N

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

• Catalyst for Suzuki coupling on a multisubstituted sp³-carbon (eq. 1)
• Catalyst for Stille coupling reaction of aryl chlorides (eq. 2)
• Catalyst for Negishi coupling reaction (eq. 3)
• Catalyst for Heck coupling to form tetrasubstituted olefins (eq. 4)
• Catalyst for Buchwald-Hartwig amination of aryl halide (eq. 5)
• Catalyst for carbonylation of aryl halides with carbamoylsilanes (eq. 6)

Catalyst for greener Heck reaction in TPGS-750-M.

On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable