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534102

Sigma-Aldrich

Methylamine solution

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33 wt. % in absolute ethanol ((denatured with 1% toluene))

Synonym(s):

Monomethylamine

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About This Item

Linear Formula:
CH3NH2
CAS Number:
74-89-5
Molecular Weight:
31.06
Beilstein:
741851
MDL number:
MFCD00008104
UNSPSC Code:
12352302
PubChem Substance ID:
24878015
NACRES:
NA.22

greener alternative product characteristics

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concentration

33 wt. % in absolute ethanol ((denatured with 1% toluene))

impurities

≤1.0% water

refractive index

n20/D 1.360-1.372

density

0.756 g/mL at 25 °C

greener alternative category

, Enabling

storage temp.

2-8°C

SMILES string

CN

InChI

1S/CH5N/c1-2/h2H2,1H3

InChI key

BAVYZALUXZFZLV-UHFFFAOYSA-N

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General description

Methylamine solution is a 33wt.% solution of methylamine in absolute ethanol. Methylamine is an aliphatic primary amine. It participates in the synthesis of isothiazolium salts. Chemical degradation of methylamine solution of γ-irradiated poly(ε-caprolactone) has been described. Maillard reaction of D-glucose and methylamine in aqueous acetic acid has been reported.
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Application

Methylamine solution in absolute ethanol can be used as a precursor that facilitates the synthesis of perovskite based materials. It can also be used as a deactivating agent to study the catalytic performance of acidic macroporous ion exchange resins. It can be annealed to reduce impurity in the grain boundaries, improve the stability and efficiency of the perovskite solar cells.

Signal Word

Danger

Hazard Statements

H225,H314,H335

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

-9.0 °F - closed cup

Flash Point(C)

-22.8 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Sigma-Aldrich

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Bianca-Maria Bresolin et al.
Nanomaterials (Basel, Switzerland), 10(1) (2020-01-16)
The development of visible-light active photocatalysts is a current challenge especially energy and environmental-related fields. Herein, methylammonium lead iodide perovskite (MAIPb) was chosen as the novel semiconductor material for its ability of absorbing visible-light. An easily reproducible and efficient method
Preparation of the MacMillan imidazolidinones.
Samulis L and Tomkinson NCO.
Tetrahedron, 67(23), 4263-4267 (2011)
Five-membered rings. II. Inter and intramolecular reactions of simple amines with N-substituted phthalimides. Methylamine as a reagent for removal of a phthaloyl group from nitrogen.
Wolfe S and Hasan SK.
Canadian Journal of Chemistry, 48(22), 3572-3579 (1970)
Formation of aromatic compounds from carbohydrates. V. Reaction of d-glucose and methylamine in slightly acidic, aqueous solution.
Olsson KJELL, et al.
Acta Chemica Scandinavica. Series B, 31(6), 469-469 (1977)
Nucleophilic Attack on Some Isothiazolium Salts.
Mckinnon DM and Hassan ME.
Canadian Journal of Chemistry, 51(18), 3081-3086 (1973)
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