521892

6-Methoxy-2-naphthaleneboronic acid

≥95%

• Synonym(s): 6-Methoxy-2-naphthalenylboronic acid, 6-Methoxy-2-naphthylboronic acid, 6-Methoxynaphthalene-2-boronic acid
• Linear Formula: C₁₀H₆OCH₃B(OH)₂
• CAS Number: 156641-98-4
• Molecular Weight: 202.01
• MDL number: MFCD03093087
• UNSPSC Code: 12352103
• PubChem Substance ID: 24874233

Properties

• Assay: ≥95%
• mp: >295 °C (lit.)
• SMILES string: COc1ccc2cc(ccc2c1)B(O)O
• InChI: 1S/C11H11BO3/c1-15-11-5-3-8-6-10(12(13)14)4-2-9(8)7-11/h2-7,13-14H,1H3
• InChI key: GZFAVYWCPSMLCM-UHFFFAOYSA-N

Description

General description

Contains varying amounts of anhydride.

Application

Reactant for:

• Suzuki-Miyaura coupling
• Enantioselective a-arylation of carbonyls via copper-bisoxazoline catalysis
• Enantioselective synthesis of aryl ketones
• Copper-catalyzed trifluoromethylation
• Rhodium-catalyzed oxidative coupling with alkynes

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves