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246921

Sigma-Aldrich

1,8-Bis(bromomethyl)naphthalene

98%

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About This Item

Linear Formula:
C10H6(CH2Br)2
CAS Number:
2025-95-8
Molecular Weight:
314.02
MDL number:
MFCD00010251
UNSPSC Code:
12352100
PubChem Substance ID:
24854836

Assay

98%

form

crystals

mp

131-133 °C (lit.)

functional group

bromo

SMILES string

BrCc1cccc2cccc(CBr)c12

InChI

1S/C12H10Br2/c13-7-10-5-1-3-9-4-2-6-11(8-14)12(9)10/h1-6H,7-8H2

InChI key

GCZOMCDXYFMAGP-UHFFFAOYSA-N

General description

Two-photon chemistry of 1,8-bis(bromomethyl)naphthalene has been studied by time-delayed, two-color photolysis and argon ion laser-jet photolysis techniques[1].

Application

1,8-Bis(bromomethyl)naphthalene has been used in the synthesis of indan-based unusual α-amino acid derivatives under solid-liquid phase-transfer catalysis conditions[2].

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCR2137
MKCP3370
MKCL6447
04130KH
10612KS

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Two-Photon Laser-Induced Reaction of 1, 8-Bis (halomethyl) naphthalenes from Different Excited States and Transient Targeting of Its Intermediate by Time-Delayed, Two-Color Photolysis and Argon Ion Laser-Jet Photolysis Techniques
Ouchi A, et al.
Journal of the American Chemical Society, 119(3), 592-599 (1997)
S Kotha et al.
The Journal of organic chemistry, 65(5), 1359-1365 (2000-05-18)
Conformationally constrained cyclic alpha-amino acid derivatives were synthesized under solid-liquid phase-transfer catalysis conditions. This methodology involves the bis-alkylation of ethyl isocyanoacetate with various alpha,alpha'-dibromo-o-xylene derivatives [alpha,alpha'-dibromo-o-xylene 5, 2,3-bis(bromomethyl)-1, 4-dimethoxybenzene 6, 1,2-bis(bromomethyl)-4,5-dibromobenzene 7, 2, 3-bis(bromomethyl)naphthalene 8, 1,8-bis(bromomethyl)-naphthalene 9, 6,7-bis(bromomethyl)-2,2-dimethyl-1H-phenalene-1,3(2H)-dione 10, 2

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