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176494

Sigma-Aldrich

Europium tris[3-(trifluoromethylhydroxymethylene)-(+)-camphorate]

Synonym(s):

Eu(facam)3, Eu(tfc)3, Europium(III) tris[3-(trifluoromethylhydroxymethylene)-d-camphorate], Tris(3-trifluoroacetyl-d-camphorato)europium(III), Tris[3-(trifluoromethylhydroxymethylene)-d-camphorato]europium(III)

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About This Item

Empirical Formula (Hill Notation):
C36H42EuF9O6
CAS Number:
34830-11-0
Molecular Weight:
893.66
EC Number:
252-232-9
MDL number:
MFCD00074803
UNSPSC Code:
12352115
PubChem Substance ID:
24850581
NACRES:
NA.22

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optical activity

[α]20/D +165°, c = 1% in chloroform (solvent is ethanol free)

technique(s)

NMR: suitable

functional group

fluoro
ketone

SMILES string

CC1(C)C2CCC1(C)C(=O)\C2=C(/O[Eu](O\C(=C3\C4CCC(C)(C3=O)C4(C)C)C(F)(F)F)O\C(=C5\C6CCC(C)(C5=O)C6(C)C)C(F)(F)F)C(F)(F)F

InChI

1S/3C12H15F3O2.Eu/c3*1-10(2)6-4-5-11(10,3)8(16)7(6)9(17)12(13,14)15;/h3*6,17H,4-5H2,1-3H3;/q;;;+3/p-3/b3*9-7-;

InChI key

BWIHMSGCCRUUCZ-NCJHBDPTSA-K

Application

Optically active NMR shift reagent. Used with Ag(fod) for the enantiomeric resolution of sec-butylisothiouronium chloride.[1]
Reactant involved in:
  • The synthesis of europium acetylcamphorate phosphine oxide complexes
  • Reactions with 1,10-N,N′-phenanthroline dioxide derivatives

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000420361
0000420360
0000420360
0000420361
0000261718

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Analytical Chemistry, 59, 562-562 (1987)

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