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CRM69368

Supelco

Buprofezin

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

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About This Item

Empirical Formula (Hill Notation):
C16H23N3OS
CAS Number:
Molecular Weight:
305.44
Beilstein:
8324923
MDL number:
UNSPSC Code:
41116107
NACRES:
NA.24

grade

certified reference material
TraceCERT®

Quality Level

product line

TraceCERT®

form

solid

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

SMILES string

CC(C)N1C(=O)N(CS\C1=N\C(C)(C)C)c2ccccc2

InChI

1S/C16H23N3OS/c1-12(2)19-14(17-16(3,4)5)21-11-18(15(19)20)13-9-7-6-8-10-13/h6-10,12H,11H2,1-5H3/b17-14+

InChI key

PRLVTUNWOQKEAI-SAPNQHFASA-N

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General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com

Buprofezin― a thiadiazine insecticide, inhibits chitin synthesis and acts as a molting inhibitor and growth regulator. It is a broad spectrum and non-systemic insecticide, that gets activated by contact and ingestion. Buprofezin inhibits molting in insect larvae and nymphs, subsequently leading to their death. It is used against beetles, leafhoppers, plant hoppers, and whiteflies among other insects for a variety of crops, vegetables, and fruits.
Buprofezin is approved for use in the European Union as a plant protection agent in the market according to the Commission Directive 2011/6/EU of 20th January 2011 repealing the Council Directive 91/414/EEC. The maximum residue level (MRL) allowed for the presence of buprofezin in plant- and animal-based products is 0.01 mg/kg as per the EU Reg 2019/91.
Buprofezin has to be monitored in the Multiannual Control Program for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
Buprofezin CRM may also find the following uses:

  • Development of a high-performance liquid chromatography-diode-array detector (HPLC-DAD) method for simultaneous analysis of buprofezin, dinobuton, and chlorothalonil in various biological, food, and environmental samples
  • Determining metolachlor and buprofezin in natural water samples by thermochemically-induced fluorescence derivatization (TIFD) method
  • To study the dissipation of acetamiprid and buprofezin in paddy grain, straw, and soil samples, in addition to their residue analysis by high-performance liquid chromatography (HPLC) with ultraviolet (UV) detection
  • Multi-residue analysis of 42 pesticides in six marijuana samples by QuEChERS extraction followed by liquid chromatography-tandem mass spectrometry (LC-MS/MS) determination
  • Quantification of 57 pesticide residues in tomato samples by liquid chromatography-electrospray ionization tandem mass spectrometry method
  • Simultaneous determination of 60 pesticide residues in various fruit and vegetable samples by using solid-phase extraction (SPE) for sample preparation and ultra-high-performance liquid chromatography/time-of-flight mass spectrometry (UHPLC/TOF-MS) for measurement

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Health hazardEnvironment

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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A novel HPLC-DAD method with dilute-and-shoot sample preparation technique for the determination of buprofezin, dinobuton and chlorothalonil in food, environmental and biological samples
Gebrehiwot WH, et al.
International Journal of Environmental Analytical Chemistry, 101(14), 2339-2353 (2021)
Daniela Daniel et al.
Journal of chromatography. A, 1603, 231-239 (2019-07-16)
A multiresidue method based on QuEChERS extraction followed liquid chromatography coupled with tandem mass spectrometry was developed and validated for the determination of 42 pesticides in marijuana. Less than 6 min is required for detection of all species. By using original
P Sivaperumal et al.
Food chemistry, 168, 356-365 (2014-08-31)
A multiresidue method, based on the sample preparation by solid-phase extraction cartridges and detection by ultra-high-performance liquid chromatography/time-of-flight mass spectrometry (UHPLC/TOF-MS), was used for the analysis of 60 pesticides in vegetable and fruit samples. Quantitation by UHPLC/TOF-MS is accomplished by

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