Yes, it can be heated above 40 °C safely. This product is packaged in an argon gas environment. It is recommended to re-dissolve the gelation under inert gas (e.g., argon) protection with gentle heating.
86710
Titanium(IV) ethoxide
Synonym(s):
Tetraethyl orthotitanate, Tetraethyl titanate
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About This Item
Linear Formula:
Ti(OC2H5)4
CAS Number:
Molecular Weight:
228.11
Beilstein:
3678992
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
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form
liquid
Quality Level
reaction suitability
core: titanium
reagent type: catalyst
impurities
≤3% tetraisopropyl orthotitanate (NMR)
refractive index
n20/D 1.505 (lit.)
n20/D 1.509
bp
150-152 °C/10 mmHg (lit.)
density
1.088 g/mL at 25 °C (lit.)
SMILES string
CCO[Ti](OCC)(OCC)OCC
InChI
1S/4C2H5O.Ti/c4*1-2-3;/h4*2H2,1H3;/q4*-1;+4
InChI key
JMXKSZRRTHPKDL-UHFFFAOYSA-N
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Application
Titanium(IV) ethoxide can be used:
- As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.[1]
- As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.[2]
- As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.[3]
Caution
During storage a gelatinous residue may form, which dissolves after heating up to 40 °C
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
107.6 °F - closed cup
Flash Point(C)
42 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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안녕하세요. 해당 제품의 specification sheet에는 gelation이 일어나며 40도 이상으로 가열하면 사라진다고 명시되어 있습니다. 제품의 인화점이 42도라고 적혀있습니다. 혹시 안전하게 가열할 수 있나요? 해당 제품은 수분에 민감하게 반응하는 것으로 알고 있는데 가열을 위해 약품통에서 꺼내는 순간 변질이 일어날 것 같습니다. 해당 제품의 gelation문제를 안전하고 변질없이 해결할 방법이 있나요?
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