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Sigma-Aldrich

Biphenyl-3,4′,5-tricarboxylic acid

greener alternative

96%

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About This Item

Empirical Formula (Hill Notation):
C15H10O6
CAS Number:
677010-20-7
Molecular Weight:
286.24
MDL number:
MFCD16621432
UNSPSC Code:
26111700
PubChem Substance ID:
329763310

Assay

96%

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

>300 °C

greener alternative category

, Enabling

SMILES string

OC(=O)c1ccc(cc1)-c2cc(cc(c2)C(O)=O)C(O)=O

InChI

1S/C15H10O6/c16-13(17)9-3-1-8(2-4-9)10-5-11(14(18)19)7-12(6-10)15(20)21/h1-7H,(H,16,17)(H,18,19)(H,20,21)

InChI key

LQEZHWGJSWHXPJ-UHFFFAOYSA-N

General description

Biphenyl-3,4′,5-tricarboxylic acid (H3BPT) is a co-ordination polymer, which is majorly used as an unsymmetrically substituted linker. It forms self-assembly under the solvothermal condition to synthesize 3D lanthanide based metal organic frameworks (MOFs).
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Application

Selected Applications of MOFs in Sustainable Energy Technologies
Biphenyl-3,4′,5-tricarboxylic acid (H3BPT) may be used to prepare porous metal-organic frameworks (MOFs) for gas adsorption, photocatalytic activity and magnetic properties. H3BPT and (bis)imidazole linkers may be used to prepare coordination polymers (CPs) by hydrothermal process. CPs may be used in gas storage, catalysis, ion exchange etc.

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H315,H319,H335,H400

Hazard Classifications

Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Crystal structures, fluorescent and magnetic properties of five new coordination polymers based on biphenyl-3, 4?, 5-tricarboxylic acid
Lu Y, et al.
Journal of Solid State Chemistry, 192, 144-152 (2012)
Two (3, 6)-connected porous metal?organic frameworks based on linear trinuclear [Co 3 (COO) 6] and paddlewheel dinuclear [Cu 2 (COO) 4] SBUs: gas adsorption, photocatalytic behaviour, and magnetic properties.
Zhao J, et al.
Journal of Material Chemistry A, 3(13), 6962-6969 (2015)
Synthesis, structure and luminescent property of a new europium-based coordination polymer constructed from biphenyl-3, 4?, 5-tricarboxylic acid.
Yan D and Duan Q
Inorganic Chemistry Communications, 36, 188-191 (2013)

Articles

Metal-Organic Frameworks in Energy

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

Metal-Organic Frameworks in Energy

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

Metal-Organic Frameworks in Energy

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

Metal-Organic Frameworks in Energy

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

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