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693111

Sigma-Aldrich

(S)-RuCl[(p-cymene)(H8-BINAP)]Cl

Synonym(s):

Chloro[(S)-(−)-2,2′−bis(diphenylphosphino)-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′−binaphthyl](p-cymene)ruthenium(II) chloride

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About This Item

Linear Formula:
[C54H54ClP2Ru]+Cl-
CAS Number:
944451-27-8
Molecular Weight:
936.93
UNSPSC Code:
12352101
PubChem Substance ID:
329761563
NACRES:
NA.22

form

powder

storage temp.

2-8°C

SMILES string

[Cl-].Cl[Ru+].C[C]1[CH][CH][C]([CH][CH]1)C(C)C.C2CCc3c(C2)ccc(P(c4ccccc4)c5ccccc5)c3-c6c7CCCCc7ccc6P(c8ccccc8)c9ccccc9

InChI

1S/C44H40P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-12,19-26,29-32H,13-18,27-28H2;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

InChI key

RDVYAXZMACLMGN-UHFFFAOYSA-L

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only.

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Articles

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

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