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461490

Sigma-Aldrich

(R)-(+)-N,N-Dimethyl-1-(1-naphthyl)ethylamine

96%

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About This Item

Linear Formula:
C10H7CH(CH3)N(CH3)2
CAS Number:
Molecular Weight:
199.29
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

96%

optical activity

[α]23/D +43°, c = 2 in methanol

refractive index

n20/D 1.591 (lit.)

bp

218 °C (lit.)

density

1 g/mL at 25 °C (lit.)

SMILES string

C[C@@H](N(C)C)c1cccc2ccccc12

InChI

1S/C14H17N/c1-11(15(2)3)13-10-6-8-12-7-4-5-9-14(12)13/h4-11H,1-3H3/t11-/m1/s1

InChI key

AXRXYILTIWBHEP-LLVKDONJSA-N

Application

(R)-(+)-N,N-Dimethyl-1-(1-naphthyl)ethylamine can react with palladium acetate in acetic acid to form cyclopalladated naphthyl adduct.
Base for kinetic resolution of alcohols and acyl halides.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Optically active cyclopalladated compounds containing P-chiral ligands. Restricted rotation around the Pd? P bond.
Albert J, et al.
Journal of Organometallic Chemistry, 634(1), 83-89 (2001)
Weidert, P.J. et al.
Liebigs Ann. Chem., 533-533 (1989)

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