Bacteria-derived enzymes that can modify specific lignin substructures are potential targets to engineer plants for better biomass processability. The Gram-negative bacterium Sphingobium sp. SYK-6 possesses a Cα-dehydrogenase (LigD) enzyme that has been shown to oxidize the α-hydroxy functionalities in β-O-4-linked
Photoswitchable fluorescent diarylethenes are promising in molecular optical memory and photonic devices. However, the performance of current diarylethenes is far from satisfactory because of the scarcity of high-speed switching capability and large fluorescence on-off ratio. Here we report a trident
Chemistry (Weinheim an der Bergstrasse, Germany), 21(46), 16479-16493 (2015-09-26)
This work describes the use of conformer-selective laser spectroscopy following supersonic expansion to probe the local folding proclivities of four-membered ring cyclic β-amino acid building blocks. Emphasis is placed on stereochemical effects as well as on the structural changes induced
The preclinical development of peptidyl drugs for cancer treatment is hampered by their poor pharmacologic properties and cell penetrative capabilities in vivo. In this study, we report a nanoparticle-based formulation that overcomes these limitations, illustrating their utility in studies of
Dalton transactions (Cambridge, England : 2003), 44(2), 598-607 (2014-11-08)
A family of zirconium complexes containing bis-, tri- or tetra-BTP ligands (BTP = benzotriazole phenolate) were synthesized and structurally characterized. Treatment of Zr(O(i)Pr)4((i)PrOH) with 2.0 molar equivalents of 2-(2H-benzotriazol-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol ((C8)BTP-H) or 2-(2H-benzotriazol-2-yl)-4,6-di-tert-butylphenol ((t-Bu)BTP-H) afforded zirconium alkoxide ([((C8)BTP)2Zr(O(i)Pr)2] (1); [((t-Bu)BTP)2Zr(O(i)Pr)2] (2))
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