404349

[Bis(trifluoroacetoxy)iodo]pentafluorobenzene

97%

• Synonym(s): FPIFA, Iodopentafluorobenzene bis(trifluoroacetate)
• Linear Formula: (CF₃CO₂)₂IC₆F₅
• CAS Number: 14353-88-9
• Molecular Weight: 519.99
• MDL number: MFCD00191612
• UNSPSC Code: 12352101
• PubChem Substance ID: 24865239
• NACRES: NA.22

Properties

• Assay: 97%
• reaction suitability: reagent type: oxidant
• mp: 117-119 °C (lit.)
• SMILES string: Fc1c(F)c(F)c([I](OC(=O)C(F)(F)F)OC(=O)C(F)(F)F)c(F)c1F
• InChI: 1S/C10F11IO4/c11-1-2(12)4(14)6(5(15)3(1)13)22(25-7(23)9(16,17)18)26-8(24)10(19,20)21
• InChI key: OQWAXRPJEPTTSZ-UHFFFAOYSA-N

Description

Application

Reactant or reagent for:

• Oxidation of organic iodides using oxone and trifluoroacetic acid
• Base hydrolysis
• Oxidative cross-coupling of arenes
• Oxidation of phenolic compounds with organohypervalent iodine
• Aziridination of alkenes
• Oxidation of organic compounds
• Oxidative fragmentation of α-amino acids or β-amino alcohols
• Oxidative biaryl coupling of thiophenes

Safety Information

• Pictograms: GHS05
• Signal Word: Danger
• Hazard Statements: H314
• Precautionary Statements: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Eye Dam. 1 - Skin Corr. 1B
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves