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281778

Sigma-Aldrich

(3-Aminopropyl)trimethoxysilane

97%

Synonym(s):

3-(Trimethoxysilyl)propylamine

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About This Item

Linear Formula:
H2N(CH2)3Si(OCH3)3
CAS Number:
13822-56-5
Molecular Weight:
179.29
Beilstein:
2038118
EC Number:
237-511-5
MDL number:
MFCD00008206
UNSPSC Code:
12352103
PubChem Substance ID:
24856993
NACRES:
NA.23
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Quality Level

200

Assay

97%

form

liquid

refractive index

n20/D 1.424 (lit.)

bp

91-92 °C/15 mmHg (lit.)

density

1.027 g/mL at 25 °C (lit.)

SMILES string

CO[Si](CCCN)(OC)OC

InChI

1S/C6H17NO3Si/c1-8-11(9-2,10-3)6-4-5-7/h4-7H2,1-3H3

InChI key

SJECZPVISLOESU-UHFFFAOYSA-N

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General description

(3-Aminopropyl) trimethoxysilane (APTMS) is an aminosilane which is used in silanization processes[1] as a silane coupling agent. It functionalizes substrates with alkoxysilane molecules.[2]
(3-Aminopropyl)trimethoxysilane(APTMS) is an amino-silane that is mainly used as a silane coupling agent for the surface modification of a variety of nanomaterials. APTMS based films form a thermally stable layer on different substrates.[3][4]

Application

APTMS can be multilayered on SiOx substrates by a layer by layer self assembly.[1] APTMS has also been used as a silane coupling agent on silver nanoparticles.[2]
APTMS is used for the synthesis of gold nano-bipyramids which can be used as substrates for C-reactive protein (CRP) antibodies that were detected by localized surface plasmon resonance(LSPR).[5] Mesoporous silica matrix can be incorporated with APTMS for the removal of chromium (Cr) from waste water.[6] It can also be used to silanize magnetic iron oxide nanoparticles(MIONPs) for the separation of cross-linked enzyme aggregations (CLEAs) from the reaction medium.[7] It may be coated on TiO2 to improve the power conversion efficiency (PCE) as a critical parameter to assess the overall performance of heterojunction perovskite solar cells (PSCs).[3]

Packaging

Optically tunable core-shell composite nanorod structures have been prepared by depositing gold onto silica and titania nanorods which have been surface modified with (3-Aminopropyl)trimethoxysilane[8]

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H315,H318

Hazard Classifications

Eye Dam. 1 - Skin Irrit. 2

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

188.6 °F - closed cup

Flash Point(C)

87 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCK5902
BCCK5789
BCCK1942
BCCK3569
BCCJ3805

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Reduction of silver nanoparticles in DMF. Formation of monolayers and stable colloids.
Pastoriza S, et al.
Pure and Applied Chemistry. Chimie Pure Et Appliquee, 72(1/2), 83-90 (2000)
Daijun Zhou et al.
International journal of nanomedicine, 13, 4157-4169 (2018-07-27)
This study aimed to prepare an eco-friendly dressing using a chitin-derived membrane with amphipathic anion/quaternary ammonium salt designed for antibacterial purposes. Four dressings were prepared and group A was chitin, group B was chitin + amphiphilic ion, group C was
Self-assembly of the 3-aminopropyltrimethoxysilane multilayers on Si and hysteretic current-voltage characteristics
Applied Physics. A, Materials Science & Processing, 90(3), 581-589 (2008)
Investigation of the mechanism of chromium removal in (3-aminopropyl) trimethoxysilane functionalized mesoporous silica.
Lee J, et al
Scientific Reports, 8(12), 103240E-103240E (2018)
Fundamental Aspects of Electrochemical Deposition and Dissolution (2000)
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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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