215333
4-Hydroxy-D-phenylglycine
≥98%
Synonym(s):
(2R)-2-Amino-2-(4-hydroxyphenyl)acetic acid
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About This Item
Linear Formula:
HOC6H4CH(NH2)CO2H
CAS Number:
Molecular Weight:
167.16
Beilstein:
2210998
EC Number:
MDL number:
UNSPSC Code:
41116107
eCl@ss:
32160406
PubChem Substance ID:
NACRES:
NA.22
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Assay
≥98%
form
solid
optical activity
[α]23/D −158±3°, c = 1 in 1 M HCl
reaction suitability
reaction type: solution phase peptide synthesis
mp
240 °C (dec.) (lit.)
application(s)
peptide synthesis
SMILES string
N[C@@H](C(O)=O)c1ccc(O)cc1
InChI
1S/C8H9NO3/c9-7(8(11)12)5-1-3-6(10)4-2-5/h1-4,7,10H,9H2,(H,11,12)/t7-/m1/s1
InChI key
LJCWONGJFPCTTL-SSDOTTSWSA-N
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Storage Class Code
13 - Non Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Alpha-amino acid derivatives, particularly those of phenylglycine, can suffer significant racemization in Suzuki couplings. When arylpinacolboronate esters are used as coupling partners this unwanted side reaction can be suppressed by the use of Pd(OAc)(2) as Pd(0) source, in the presence
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