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Supelco

Aldicarb-sulfone

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C7H14N2O4S
CAS Number:
1646-88-4
Molecular Weight:
222.26
Beilstein:
2215242
EC Number:
216-710-0
MDL number:
MFCD00041804
UNSPSC Code:
41116107
PubChem Substance ID:
329754515
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
NMR: suitable
gas chromatography (GC): suitable

impurities

≤0.5% water (Karl Fischer)

mp

132-135 °C

suitability

passes test for identity (NMR)

application(s)

agriculture
environmental

format

neat

SMILES string

CNC(ON=CC(C)(C)S(C)(=O)=O)=O

InChI

1S/C7H14N2O4S/c1-7(2,14(4,11)12)5-9-13-6(10)8-3/h5H,1-4H3,(H,8,10)

InChI key

YRRKLBAKDXSTNC-UHFFFAOYSA-N

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General description

Aldicarb-sulfone is a metabolite of the insecticide aldicarb used to control insects, mites and nematodes in agricultural crops.

Application

Aldicarb-sulfone may be used as a reference standard for the determination of the analyte in tobacco using high-performance liquid chromatography with dual post-column reaction and fluorescence detection.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

Signal Word

Danger

Hazard Statements

H300 + H310 + H330,H400

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCH0182
BCBW8057
BCBS8694V
SZBC313XV
SZBB343XV

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Y Picó et al.
Food additives and contaminants, 7 Suppl 1, S29-S34 (1990-01-01)
Aldicarb was applied to the soil of Late Valencia orange field plots. A comparative study between four analytical methods is reported, the NPD-gas chromatography method being the best choice. The work also reports the study of accumulation and persistence of
Transport of organic contaminants in groundwater: gas chromatography model to forecast the significance as applied to aldicarb sulfone residues.
J P Mestres et al.
Archives of environmental contamination and toxicology, 16(6), 649-656 (1987-11-01)
Persistence and metabolism of aldicarb in fresh potatoes.
T Cairns et al.
Bulletin of environmental contamination and toxicology, 32(3), 274-281 (1984-03-01)
D X Lian et al.
Journal of chromatography, 542(2), 526-530 (1991-04-12)
A method is described for the determination of aldicarb and its metabolites (the sulphoxide and sulphone) in urine by gas chromatography with flame photometric detection (GC-FPD). The sample was concentrated with a column containing activated charcoal and Florisil, and then
W P Cochrane et al.
Journal - Association of Official Analytical Chemists, 64(3), 724-728 (1981-05-01)
An ion-suppression reverse phase high pressure liquid chromatographic method is described for the determination of aldicarb, aldicarb sulfoxide, and aldicarb sulfone in potatoes. Samples are extracted with methylene chloride and Na2SO4, evaporated to dryness, and cleaned up using Sep-Pak silica
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