697605

(S,S)-ANDEN-Phenyl Trost Ligand

• Synonym(s): (+)-(11S,12S)Bis[2′-(diphenylphosphino)benzamido]-9,10-dihydro-9,10-ethanoanthracene, (11S,12S)-N,N′-(9,10-Dihydro-9,10-ethanoanthracene-11,12-diyl)bis[2-(diphenylphosphino)]benzamide
• Empirical Formula (Hill Notation): C₅₄H₄₂N₂O₂P₂
• CAS Number: 138517-65-4
• Molecular Weight: 812.87
• MDL number: MFCD12546008
• UNSPSC Code: 12352002
• PubChem Substance ID: 329761936

Properties

• optical activity: [α]22/D +111°, c = 1 in chloroform
• mp: 123-128 °C
• SMILES string: O=C(N[C@@H]1[C@@H](NC(=O)c2ccccc2P(c3ccccc3)c4ccccc4)[C@H]5c6ccccc6[C@@H]1c7ccccc57)c8ccccc8P(c9ccccc9)c%10ccccc%10
• InChI: 1S/C54H42N2O2P2/c57-53(45-33-17-19-35-47(45)59(37-21-5-1-6-22-37)38-23-7-2-8-24-38)55-51-49-41-29-13-15-31-43(41)50(44-32-16-14-30-42(44)49)52(51)56-54(58)46-34-18-20-36-48(46)60(39-25-9-3-10-26-39)40-27-11-4-12-28-40/h1-36,49-52H,(H,55,57)(H,56,58)/t49-,50+,51-,52-/m0/s1
• InChI key: BEKZNCOFLFMFHP-UYATXGGZSA-N

Description

Application

Asymmetric allylic alkylation ligand.

Legal Information

Sold in collaboration with Dr. Reddy′s Laboratories for research purposes only.

Safety Information

• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves