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481521

Sigma-Aldrich

Hexaamminecobalt(III) chloride

99%

Synonym(s):

Cobalt hexammine trichloride, Hexaamminecobalt trichloride

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About This Item

Linear Formula:
[Co(NH3)6]Cl3
CAS Number:
10534-89-1
Molecular Weight:
267.48
EC Number:
234-103-9
MDL number:
MFCD00036304
UNSPSC Code:
12352302
PubChem Substance ID:
24871764
NACRES:
NA.23

Assay

99%

form

powder

mp

217 °C (lit.)

solubility

H2O: slightly soluble(lit.)
ethanol: insoluble(lit.)

density

1.71 g/mL at 25 °C (lit.)

SMILES string

N.N.N.N.N.N.[Cl-].[Cl-].[Cl-].[Co+3]

InChI

1S/3ClH.Co.6H3N/h3*1H;;6*1H3/q;;;+3;;;;;;/p-3

InChI key

JXBGZYGSWFSYFI-UHFFFAOYSA-K

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General description

Hexaamminecobalt(III) chloride can be used as a starting material to prepare various Co-based nanomaterials such as Co-Sb nanoalloys, Co nanocapsules, bimetallic nanoparticles, and Co-polymer nanocomposites. These materials are applied in the field of catalysis, dielectrics, and renewable energy conversion devices.

Application

  • Rhenium (VII) compounds as inorganic precursors for the synthesis of organic reaction catalysts: Investigates the potential of Hexaamminecobalt(III) chloride as a replacement for commercial products in catalyzing organic reactions, highlighting its role in synthetic chemistry (K Leszczyńska-Sejda et al., 2019).
  • In situ formation of a molecular cobalt (iii)/AgCl photocatalyst for visible-light water oxidation: Discusses the synthesis and application of Hexaamminecobalt(III) chloride in forming a novel photocatalyst for water oxidation, a critical process in solar energy utilization (H Mogi et al., 2021).

Pictograms

Health hazard
GHS08

Signal Word

Danger

Hazard Statements

H317,H334,H351,H413

Hazard Classifications

Aquatic Chronic 4 - Carc. 2 - Resp. Sens. 1 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Bimetallic Pd-M (M?=?Pt, Ni, Cu, Co) nanoparticles catalysts with strong electrostatic metal-support interaction for hydrogenation of toluene and benzene
Jingyi Yang, et al.
Molecular Catalysis, 492, 110992-110992 (2020)
Sb-modulated synthesis of novel CoSb alloy nanoparticles anchored on N-doped carbon as oxygen electrocatalysts
Tao Gong, et al.
Applied Surface Science, 562, 150112-150112 (2021)
Synthesis of Co nanocapsules coated with BN layers by annealing of KBH4 and [Co(NH3)6]Cl3
Ichihito Narita, et al.
Solid State Communications, 137, 44-48 (2006)
Fabrication of a novel PANI/[Co (NH3)4 (C3H4N2)2]Cl3 nanocomposite with enhanced dielectric constant and ac-conductivity
Waseem Naqash and Kowsar Majid
Journal of Materials Science: Materials in Electronics, 28, 14217-14225 (2017)
Tumpa Sarkar et al.
Nucleic acids research, 33(1), 143-151 (2005-01-11)
The condensation of nucleic acids into well-defined particles is an integral part of several approaches to artificial cellular delivery. Improvements in the efficiency of nucleic acid delivery in vivo are important for the development of DNA- and RNA-based therapeutics. Presently
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