377147

1,1-Bis(diphenylphosphino)ethylene

98%

• Synonym(s): VDPP, Vinylidenebis(diphenylphosphine)
• Linear Formula: [(C₆H₅)₂P]₂C=CH₂
• CAS Number: 84494-89-3
• Molecular Weight: 396.40
• MDL number: MFCD00191809
• UNSPSC Code: 12352002
• PubChem Substance ID: 24863495

Properties

• Assay: 98%
• form: solid
• reaction suitability: reagent type: ligand
• mp: 110-111 °C (lit.)
• functional group: phosphine
• SMILES string: C=C(P(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
• InChI: 1S/C26H22P2/c1-22(27(23-14-6-2-7-15-23)24-16-8-3-9-17-24)28(25-18-10-4-11-19-25)26-20-12-5-13-21-26/h2-21H,1H2
• InChI key: GEGLBMPXRFOXTK-UHFFFAOYSA-N

Description

Application

Reactant for preparation of:

• Cyclometallated palladium diphosphane catalysts by Michael addition reactions
• A-frame structures with palladacycles (chelating agent)
• Functionalized bis-phosphine monoxide ligands catalyzed by chiral palladacycles
• Tetranuclear palladacycles with bridging diphosphine ligands
• Tetranuclear bromide-bridged Cu(I) complexes

• Used as carbon-bridged diphosphine ligand in Cr-catalyzed ethylene tri- and tetramerization reactions

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves