Skip to Content
Merck
All Photos(2)

Documents

230502

Sigma-Aldrich

Copper(I) bromide dimethyl sulfide complex

99%

Synonym(s):

Copper(I) bromide methyl sulfide complex, Cuprous bromide dimethyl sulfide complex, Cuprous bromide methyl sulfide complex

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
CuBr · CH3SCH3
CAS Number:
54678-23-8
Molecular Weight:
205.58
Beilstein:
4386581
EC Number:
259-292-5
MDL number:
MFCD00043295
UNSPSC Code:
12161600
PubChem Substance ID:
24853810
NACRES:
NA.22

Assay

99%

form

solid

reaction suitability

core: copper
reagent type: catalyst

mp

132 °C (dec.) (lit.)

SMILES string

[Cu]Br.CSC

InChI

1S/C2H6S.BrH.Cu/c1-3-2;;/h1-2H3;1H;/q;;+1/p-1

InChI key

PMHQVHHXPFUNSP-UHFFFAOYSA-M

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application

Catalyst employed in the addition of Grignard reagents (alkyl, alkenyl, aryl) to fullerenes. This process adds 5 organic groups to [60]fullerene and 3 groups to [70]fullerene.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Rossiter, B. E. et al.B. E.; Swingle, N. M.
Chemical Reviews, 92, 771-771 (1992)
Enantioselective Cu-catalyzed 1,4-addition of Grignard reagents to cyclohexenone using taddol-derived phosphine-phosphite ligands and 2-methyl-THF as a solvent.
Tobias Robert et al.
Angewandte Chemie (International ed. in English), 47(40), 7718-7721 (2008-09-06)
Beatriz Pacheco Berciano et al.
Organic letters, 12(18), 4038-4041 (2010-08-26)
The copper-catalyzed direct alkynylation of azoles with 1,1-dibromo-1-alkenes as electrophiles is described. These easily accessible substrates are a useful addition to the field of direct alkynylations in an efficient and functional group tolerant reaction to provide a straightforward entry to
Organic Syntheses, 83, 80-80 (2006)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service