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203866

Sigma-Aldrich

Nickel(II) chloride hexahydrate

99.999% trace metals basis

Synonym(s):

Dichloronickel hexahydrate, Nickel dichloride hexahydrate

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About This Item

Linear Formula:
NiCl2 · 6H2O
CAS Number:
Molecular Weight:
237.69
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Assay

99.999% trace metals basis

form

crystals and lumps

impurities

≤15.0 ppm Trace Metal Analysis

application(s)

battery manufacturing

SMILES string

[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Ni]Cl

InChI

1S/2ClH.Ni.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2

InChI key

LAIZPRYFQUWUBN-UHFFFAOYSA-L

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Application

Nickel(II) chloride hexahydrate can be used:
  • As a precursor to synthesize nickel(ll) complexes, such as nickel complexes of dithiocarbimates derived from sulfonamides.
  • To fabricate Ni-based composites for various applications such as photocatalysis.
  • As a catalyst for various organic reactions, for example, synthesis of tetra-substituted pyrroles and cleavage of tetrahydropyranyl (THP) and tert-butyldimethylsilyl (TBS) ethers.
  • As a starting material to prepare NiO nanoparticles.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

Target Organs

Lungs

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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William G Brumbaugh et al.
Environmental toxicology and chemistry, 32(11), 2482-2494 (2013-05-10)
Two spiking methods were compared and nickel (Ni) partitioning was evaluated during a series of toxicity tests with 8 different freshwater sediments having a range of physicochemical characteristics. A 2-step spiking approach with immediate pH adjustment by addition of NaOH
John M Besser et al.
Environmental toxicology and chemistry, 32(11), 2495-2506 (2013-05-10)
This study evaluated the chronic toxicity of Ni-spiked freshwater sediments to benthic invertebrates. A 2-step spiking procedure (spiking and sediment dilution) and a 2-stage equilibration period (10 wk anaerobic and 1 wk aerobic) were used to spike 8 freshwater sediments with wide
Ritu Tyagi et al.
Journal of applied toxicology : JAT, 33(2), 134-141 (2011-09-20)
Heavy metals are known for their associated nephrotoxicity and nickel is no exception. An integrated metabonomic approach, based on high-resolution (1) H NMR spectroscopy, was applied to determine the acute biochemical effects of NiCl(2) on the renal tissues of rats.
Terran E Bergdale et al.
Journal of biotechnology, 161(3), 181-189 (2012-07-14)
Microbiologically induced calcium carbonate precipitation (MICCP) is a naturally occurring biological process that has shown its potential in remediation of a wide range of structural damages including concrete cracks. In this study, genetically engineered microorganisms, capable of producing extracellular polymeric
Rebekka Kubisch et al.
Sensors (Basel, Switzerland), 12(3), 3370-3393 (2012-06-28)
Pollution of drinking water sources represents a continuously emerging problem in global environmental protection. Novel techniques for real-time monitoring of water quality, capable of the detection of unanticipated toxic and bioactive substances, are urgently needed. In this study, the applicability

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