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45642

Supelco

Propiconazole

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C15H17Cl2N3O2
CAS Number:
Molecular Weight:
342.22
Beilstein:
9349305
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24
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grade

analytical standard

Quality Level

description

mixture of stereo isomers

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CCCC1COC(Cn2cncn2)(O1)c3ccc(Cl)cc3Cl

InChI

1S/C15H17Cl2N3O2/c1-2-3-12-7-21-15(22-12,8-20-10-18-9-19-20)13-5-4-11(16)6-14(13)17/h4-6,9-10,12H,2-3,7-8H2,1H3

InChI key

STJLVHWMYQXCPB-UHFFFAOYSA-N

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General description

Propiconazole is a systemic fungicide and its mode of action involves the inhibition of ergosterol biosynthesis.[1]

Application

Propiconazole may be used as an analytical reference standard for the quantification of the analyte in must,[2] wine samples[2] and environmental samples[3] using different chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 1B - Skin Sens. 1

Storage Class Code

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

392.0 °F - Pensky-Martens closed cup

Flash Point(C)

200 °C - Pensky-Martens closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH Annex XVII (Restriction List)

CAS No.

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Certificates of Analysis (COA)

Lot/Batch Number

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70th International Symposium on Molecular Spectroscopy (2004)
HPLC method for simultaneous determination of fungicides: carbendazim, metalaxyl, folpet, and propiconazole in must and wine
Lopez F.L, et al.
Journal of Agricultural and Food Chemistry, 37(3), 684-687 (1989)
Jet C Van De Steene et al.
Journal of the American Society for Mass Spectrometry, 19(5), 713-718 (2008-03-18)
When developing an LC-MS/MS-method matrix effects are a major issue. The effect of co-eluting compounds arising from the matrix can result in signal enhancement or suppression. During method development much attention should be paid to diminishing matrix effects as much
Thomas Hartwig et al.
PloS one, 7(5), e36625-e36625 (2012-05-17)
Brassinosteroids (BRs) are steroidal hormones that play pivotal roles during plant development. In addition to the characterization of BR deficient mutants, specific BR biosynthesis inhibitors played an essential role in the elucidation of BR function in plants. However, high costs
Arthur W Garrison et al.
International journal of environmental research and public health, 8(8), 3453-3467 (2011-09-13)
Propiconazole is a chiral fungicide used in agriculture for control of many fungal diseases on a variety of crops. This use provides opportunities for pollution of soil and, subsequently, groundwater. The rate of loss of propiconazole from the water phase

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. 프로피코나졸의 경우 다른 트리아졸계열 약제와는 다르게 액체상태로 오게 되는데 총 볼륨이 몇이고 용매가 무엇인지 궁금합니다. 추가로 해당 약제는 상온에서 얼마나 보관할 수 있는지 알고싶습니다.

    1 answer
    1. The storage duration at room temperature for this product is not tested, so no specific time frame is available. This product should be stored refrigerated. According to the Chemical Abstracts Service, the density is 1.398 g/cm³, which means approximately 178.8 microliters are in the 250 mg pack size. It is recommended to use a calibrated pipet to transfer the material if the volume is critical, as the material is typically overfilled by a small amount.

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