279730
Tris(dimethylamino)borane
97%
Synonym(s):
Hexamethylboranetriamine, NSC 379532
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About This Item
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Quality Level
Assay
97%
form
liquid
reaction suitability
reagent type: reductant
refractive index
n20/D 1.446 (lit.)
bp
147-148 °C (lit.)
mp
−16 °C (lit.)
density
0.817 g/mL at 25 °C (lit.)
functional group
amine
SMILES string
CN(C)B(N(C)C)N(C)C
InChI
1S/C6H18BN3/c1-8(2)7(9(3)4)10(5)6/h1-6H3
InChI key
SOLWORTYZPSMAK-UHFFFAOYSA-N
General description
Tris(dimethylamino)borane is an organoborane generally used as a macrolactamization reagent. It can also be used to prepare tris(alkylamino)borane analogs by transamination of primary and secondary amines.
Application
Reactant involved in:
- B-C-N hybrid films deposited on Ni
- Reduction reactions
- Syntehsis of lithium borom imidazolate framework polymeric complexes
- One-pot oxidative amination
- Synthesis of boron salts and tripodal borate ligands
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
-5.8 °F - closed cup
Flash Point(C)
-21 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Tris(dimethylamino)borane
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2008)
Tetrahedron Letters, 32, 639-639 (1991)
Journal of Organometallic Chemistry, 303, 324-324 (1986)
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