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Key Documents

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46318

Supelco

Sulcotrione

PESTANAL®, analytical standard

Sinónimos:

2-[2-Chloro-4-(methylsulfonyl)benzoyl]-1,3-cyclohexanedione

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About This Item

Fórmula empírica (notación de Hill):
C14H13ClO5S
Número de CAS:
99105-77-8
Peso molecular:
328.77
Beilstein/REAXYS Number:
8155739
MDL number:
MFCD01632349
UNSPSC Code:
41116107
PubChem Substance ID:
329757134
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CS(=O)(=O)c1ccc(c(Cl)c1)C(=O)C2C(=O)CCCC2=O

InChI

1S/C14H13ClO5S/c1-21(19,20)8-5-6-9(10(15)7-8)14(18)13-11(16)3-2-4-12(13)17/h5-7,13H,2-4H2,1H3

InChI key

PQTBTIFWAXVEPB-UHFFFAOYSA-N

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General description

Sulcotrione is a herbicide belonging to the triketone class, commonly used in corn production.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Sulcotrione may be used as an analytical reference standard for the quantification of the analyte in environmental samples using liquid chromatography coupled to tandem mass spectrometry.

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Warning

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2 - Skin Sens. 1A - STOT RE 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificados de análisis (COA)

Lot/Batch Number
BCCK2261
BCBZ6817
SZBE036XV
SZBB055XV
SZE6079X

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Visite la Librería de documentos

Hanene Chaabane et al.
Journal of agricultural and food chemistry, 53(10), 4091-4095 (2005-05-12)
The retention process of sulcotrione and its two hydrolysis products, 1,3-cyclohexanedione (CHD) and 2-chloro-4-methylsulfonylbenzoic acid (CMBA), were studied in four different soils (Belgium, Landes, Perpignan, and Martinique) under laboratory conditions. Adsorption isotherms were well fitted by a Freundlich relationship. The
Soil dissipation of the post-emergence herbicide sulcotrione in maize crops treated with organic fertilizers.
J Rouchaud et al.
Bulletin of environmental contamination and toxicology, 57(3), 398-405 (1996-09-01)
Sulcotrione soil metabolism in summer corn crops.
J Rouchaud et al.
Bulletin of environmental contamination and toxicology, 61(5), 669-676 (1998-12-05)
Jaroslaw Wiszniowski et al.
Chemosphere, 74(9), 1224-1230 (2008-12-30)
One of the strategies for decreasing the consumption of herbicides consists in improving their uptake and efficiency. It was suggested that the photodegradation of herbicides due to sunlight results in a greater demand of herbicides to be introduced into the
Luciana Gomides Freitas et al.
Journal of chromatography. A, 1028(2), 277-286 (2004-03-03)
The LC/ESI/MSMS method allows the trace quantification (ng/l) of the new triketone herbicides, i.e. sulcotrione and mesotrione, and important herbicides and metabolites, in natural waters. Solid phase extraction (SPE) for sample enrichment is performed with OASIS (recoveries 94-112% for parent
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