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45554

Supelco

Maneb

PESTANAL®, analytical standard

Sinónimos:

Manganese ethylenebis(dithiocarbamate)

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About This Item

Fórmula lineal:
[C4H6MnN2S4]n
Número de CAS:
12427-38-2
Beilstein/REAXYS Number:
3747585
EC Number:
235-654-8
MDL number:
MFCD00046858
UNSPSC Code:
41116107
PubChem Substance ID:
329756824
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

mol wt

Mw 265.30 (as monomer)

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

S=C1NCCNC(=S)S[Mn]S1

InChI

1S/C4H8N2S4.Mn/c7-3(8)5-1-2-6-4(9)10;/h1-2H2,(H2,5,7,8)(H2,6,9,10);/q;+2/p-2

InChI key

YKSNLCVSTHTHJA-UHFFFAOYSA-L

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General description

Maneb is a manganese containing wide spectrum fungicide that belongs to the class of ethylene bis-dithiocarbamate (EBDC) compounds. It is commonly used to protect crops such as apples, pears, tobacco, grains, and beets.

Application

The maneb analytical standard can be used:

  • For the simultaneous determination of maneb along with its main metabolites from tomatoes using liquid chromatography
  • In the supramolecular liquid phase microextraction based UV-Vis spectrophotometric determination of maneb in food and water samples
  • For the spectrophotometric determination of maneb with 1-(2′-Pyridylazo)-2-naphthol (PAN)
  • To determine Maneb, Zineb, and their decomposition product with 2,6-dibromoquinone chlorimide (DBQ) and 2,6-dichloroquinone chlorimide (DCQ) by spectrophotometry

Other Notes

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 2 - Skin Sens. 1

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificados de análisis (COA)

Lot/Batch Number
BCCD8573
BCBW3049
SZB9030XV
SZE9030X
9030X

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A L Rao et al.
Talanta, 40(2), 201-203 (1993-02-01)
A rapid, sensitive, simple and selective spectrophotometric method has been developed for the determination of micro-quantities of maneb (manganese ethylenebisdithiocarbamate) after extraction of the manganese-PAN complex in isobutyl methyl ketone (MIBK). The complex absorbs strongly at 550 nm. Beer's law
Mustafa Soylak et al.
Food chemistry, 338, 128068-128068 (2020-09-20)
A novel and green method was developed for enrichment of maneb (manganese ethylene-bisdithiocarbamate) with a supramolecular solvent liquid phase microextraction method. The microextraction method has been used for the first time in the literature for separation-preconcentration of maneb. 1-decanol and
G Meco et al.
Scandinavian journal of work, environment & health, 20(4), 301-305 (1994-08-01)
Permanent parkinsonism was observed in a man with chronic exposure to the fungicide maneb (manganese ethylene-bis-dithiocarbamate). Symptoms developed at 37 years of age, two years after exposure had ceased. To our knowledge, this is the second report on parkinsonism associated
Emanuela Corsini et al.
Toxicology and applied pharmacology, 208(2), 178-185 (2005-05-17)
Available data suggest that ethylenebisdithiocarbamates (EBDCs) may have immunomodulatory effects. This study aimed to investigate the immunological profile of farmers exposed to Mancozeb, an EBDC fungicide, through the determination of several serum, cellular, and functional immune parameters. Twenty-six healthy subjects
R M Garcinuño et al.
Journal of chromatography. A, 1043(2), 225-229 (2004-08-28)
Liquid chromatography (LC) with diode array ultraviolet absorbance (DAD UV) detection is used for the simultaneous determination of the fungicide maneb and its main metabolites (ethylenethiourea--ETU, ethylenebis (isothiocyanate) sulfide--EBIS, and ethyleneurea--EU) in tomatoes. The identity of EBIS, one of the
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