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Merck

45520

Supelco

Glufosinate-ammonium

PESTANAL®, analytical standard

Sinónimos:

2-Amino-4-(hydroxymethylphosphinyl)butyric acid ammonium salt, DL-Phosphinothricin

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About This Item

Fórmula empírica (notación de Hill):
C5H15N2O4P
Número de CAS:
Peso molecular:
198.16
Beilstein/REAXYS Number:
8163399
EC Number:
MDL number:
UNSPSC Code:
41116107
eCl@ss:
39110524
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

mp

215 °C

application(s)

agriculture
environmental

format

neat

SMILES string

N.CP(O)(=O)CCC(N)C(O)=O

InChI

1S/C5H12NO4P.H3N/c1-11(9,10)3-2-4(6)5(7)8;/h4H,2-3,6H2,1H3,(H,7,8)(H,9,10);1H3

InChI key

ZBMRKNMTMPPMMK-UHFFFAOYSA-N

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General description

Glufosinate-ammonium is a phosphinic acid analog of glutamic acid.

Application

Glufosinate-ammonium may be used as a reference standard for the determination of the analyte in:
  • Human serum samples by mixed-mode solid-phase extraction (SPE), tert-butyldimethylsilyl (t-BDMS) derivatization and gas chromatography-mass spectrometry (GC-MS) operating on electron impact (EI) mode of detection.
  • Water samples by ion-exchange cleanup and derivatization followed by analysis using GC coupled to tandem mass spectrometry (MS/MS) equipped with EI mode of detection.
  • Finnish arable soils by high performance liquid chromatography combined with fluorescence detection (HPLC-FLD).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Health hazardExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Repr. 1B - STOT RE 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Certificados de análisis (COA)

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Los clientes también vieron

Determination of glufosinate ammonium and its metabolite, 3-methylphosphinicopropionic acid, in human serum by gas chromatography-mass spectrometry following mixed-mode solid-phase extraction and t-BDMS derivatization.
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Journal of Analytical Toxicology, 25(8), 680-684 (2001)
Ji-Hui Byeon et al.
Biochemical and biophysical research communications, 441(1), 243-248 (2013-10-22)
We present an efficient method for the production of N-acetyl-L-phosphinothricin (N-AcPt) from commercial DL-phosphinothricin (DL-PPT) by organic acetylation for use as a negative selection agent (NSA) that induces cell death in argE transgenic rice. DL-PPT was efficiently converted into N-AcPt
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PloS one, 10(3), e0118476-e0118476 (2015-03-04)
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Determination of glufosinate ammonium and its metabolite (AE F064619 and AE F061517) residues in water by gas chromatography with tandem mass spectrometry after ion exchange cleanup and derivatization.
Royer A, et al.
Journal of Agricultural and Food Chemistry, 48(11), 5184-5189 (2000)
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Artículos

Glyphosate and related compounds are measured in oatmeal and infant cereal using ion-exchange polymer-based particles for HPLC and SPE. Low level detection was obtained.

Glyphosate and related compounds are measured in oatmeal and infant cereal using ion-exchange polymer-based particles for HPLC and SPE. Low level detection was obtained.

Glyphosate and related compounds are measured in oatmeal and infant cereal using ion-exchange polymer-based particles for HPLC and SPE. Low level detection was obtained.

Glyphosate and related compounds are measured in oatmeal and infant cereal using ion-exchange polymer-based particles for HPLC and SPE. Low level detection was obtained.

Ver todo

Protocolos

Protocol for LC/MS Analysis of Glyphosate and Metabolites on apHera™ NH2, 2 mm I.D. Column

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