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Merck

32964

Supelco

Metrafenone

PESTANAL®, analytical standard

Sinónimos:

(3-Bromo-6-methoxy-2-methylphenyl)(2,3,4-trimethoxy-6-methylphenyl)methanone, 3′-Bromo-2,3,4,6′-tetramethoxy-2′,6-dimethylbenzophenone

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About This Item

Fórmula empírica (notación de Hill):
C19H21BrO5
Número de CAS:
Peso molecular:
409.27
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

COc1ccc(Br)c(C)c1C(=O)c2c(C)cc(OC)c(OC)c2OC

InChI

1S/C19H21BrO5/c1-10-9-14(23-4)18(24-5)19(25-6)15(10)17(21)16-11(2)12(20)7-8-13(16)22-3/h7-9H,1-6H3

Inchi Key

AMSPWOYQQAWRRM-UHFFFAOYSA-N

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General description

Metrafenone is a novel benzophenone fungicide that could be used against powdery mildew and eye spot in vegetables and fruits.

Application

Metrafenone may be used as an analytical reference standard for the determination of the analyte in:
  • Vegetables by gas chromatography coupled to electron capture detector (GC-ECD).
  • Honeybees by liquid and gas chromatography combined with tandem mass spectrometry (LC-MS/MS and GC-MS/MS).
  • Animal samples and earthworms by LC-MS/MS.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Environment

signalword

Warning

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves


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Certificados de análisis (COA)

Lot/Batch Number

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Visite la Librería de documentos

Dorothée Siou et al.
Applied and environmental microbiology, 81(3), 957-965 (2014-11-25)
Head blight (HB) is one of the most damaging diseases on wheat, inducing significant yield losses and toxin accumulation in grains. Fungal pathogens responsible for HB include the genus Microdochium, with two species, and the toxin producer genus Fusarium, with
Determination of metrafenone in bitter gourd and soil by GC with ECD.
Wang S, et al.
Food Chemistry, 196, 170-173 (2016)
Jianjun Li et al.
Food chemistry, 214, 77-81 (2016-08-11)
A simple method for determination of metrafenone in vegetables by matrix solid-phase dispersion (MSPD) and HPLC was developed. All vegetable samples were extracted with dichloromethane, and then the extracts were directly separated on a reversed-phase column with isocratic elution without
Determination of metrafenone in vegetables by matrix solid-phase dispersion and HPLC-UV method.
Li J, et al.
Food Chemistry, 214, 77-81 (2017)
A liquid chromatography-electrospray tandem mass spectrometry method for the determination of multiple pesticide residues involved in suspected poisoning of non-target vertebrate wildlife, livestock and pets.
Taylor MJ, et al.
Analytical Methods : Advancing Methods and Applications, 5(1), 248-259 (2013)

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