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Merck

32606

Supelco

Fumonisin B3 solution

~50 μg/mL in acetonitrile: water, analytical standard

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About This Item

Fórmula empírica (notación de Hill):
C34H59NO14
Número de CAS:
Peso molecular:
705.83
Beilstein/REAXYS Number:
8181181
MDL number:
UNSPSC Code:
85151701
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

shelf life

limited shelf life, expiry date on the label

concentration

~50 μg/mL in acetonitrile: water

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

solubility

water: soluble

application(s)

cleaning products
cosmetics
food and beverages
personal care

format

single component solution

storage temp.

−20°C

SMILES string

CCCC[C@@H](C)[C@@H](OC(=O)CC(CC(O)=O)C(O)=O)[C@H](C[C@@H](C)C[C@H](O)CCCCCC[C@H](O)[C@@H](C)N)OC(=O)CC(CC(O)=O)C(O)=O

InChI

1S/C34H59NO14/c1-5-6-11-21(3)32(49-31(43)19-24(34(46)47)17-29(40)41)27(48-30(42)18-23(33(44)45)16-28(38)39)15-20(2)14-25(36)12-9-7-8-10-13-26(37)22(4)35/h20-27,32,36-37H,5-19,35H2,1-4H3,(H,38,39)(H,40,41)(H,44,45)(H,46,47)/t20-,21+,22+,23?,24?,25+,26-,27-,32+/m0/s1

InChI key

CPCRJSQNWHCGOP-ZBUYIUKQSA-N

General description

Certan Vial
Fumonisins are mycotoxins, produced by molds of genus Fusarium. Six types of fumonisins and their structures have been discovered: fumonisin (B1, B2, B3, B4, A1 and A2). Fumonisins are responsible for toxic properties of corn contaminated with Fusarium moniliforme. Simultaneous determination of fumonisin B1, fumonisin B2 and fumonisin B3 in traditional chinese medicines by ultra-high-performance liquid chromatography-tandem mass spectrometry is reported.

Application

Fumonisin B3 may be used as a reference standard for the determination of the analyte in food supplements using liquid chromatography coupled with tandem mass spectrometry (LC-MS/MS).
Fumonisin B3 solution was used as analytical standard in determination of fumonisins in stored wheat samples by HPLC analysis. It may be used as analytical standard in determination of fumonisins B1, B2, and B3 and hydrolyzed fumonisin B1 in corn containing foods.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Analysis Note

purity : ≥95.0% (HPLC)

pictograms

FlameExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

42.8 °F - not determined

flash_point_c

6 °C - not determined

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Edwin Palencia et al.
The Journal of nutrition, 133(10), 3200-3203 (2003-10-02)
Fumonisin B1 (FB1) is a maize mycotoxin. In tortilla preparation, maize is treated with lime (nixtamalization), producing hydrolyzed FB1 (HFB1) due to loss of the tricarballylic acid side chains. This study determined the following: 1) whether nixtamalization by Mayan communities
A E Desjardins et al.
Molecular plant-microbe interactions : MPMI, 15(11), 1157-1164 (2002-11-09)
We have analyzed the role of fumonisins in infection of maize (Zea mays) by Gibberella moniliformis (anamorph Fusarium verticillioides) in field tests in Illinois and Iowa, United States. Fumonisin-nonproducing mutants were obtained by disrupting FUM1 (previously FUM5), the gene encoding
L van der Westhuizen et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 27(11), 1582-1588 (2010-09-14)
In the Centane magisterial area of South Africa, high rates of oesophageal cancer have been associated with home-grown maize contaminated with fumonisins. The aim of this study was to implement a simple intervention method to reduce fumonisin exposure in a
Liana van der Westhuizen et al.
Journal of agricultural and food chemistry, 51(18), 5574-5578 (2003-08-21)
In Brazil, the southern region has the highest incidence of esophageal cancer and also the highest production and consumption of corn (Zea mays) products. Corn samples intended for human consumption from the western, northern, and southern regions of the state
Zheng Han et al.
Journal of separation science, 33(17-18), 2723-2733 (2010-08-24)
A reliable isotope dilution method for simultaneous determination of fumonisin B1, fumonisin B2 and fumonisin B3 in traditional Chinese medicines by ultra-high-performance LC-MS/MS was developed, and a special focus was placed on the optimization of extraction, cleanup, ultra-high-performance LC separation

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