11291

1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

≥97.0% (NMR)

• Sinónimos: EMIM BTI, EMIM TFSI, EMIMIm
• Fórmula empírica (notación de Hill): C₈H₁₁F₆N₃O₄S₂
• Número de CAS: 174899-82-2
• Peso molecular: 391.31
• Número MDL: MFCD03788927
• Código UNSPSC: 12352100
• ID de la sustancia en PubChem: 329749349
• NACRES: NA.22

Propiedades

• Nivel de calidad: 100
• Ensayo: ≥97.0% (NMR)
• Formulario: liquid
• impurezas: <0.5% water
• mp: ≥−15 °C (lit.)
• grupo funcional: fluoro
• cadena SMILES: CCn1cc[n+](C)c1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F
• InChI: 1S/C6H11N2.C2F6NO4S2/c1-3-8-5-4-7(2)6-8;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h4-6H,3H2,1-2H3;/q+1;-1
• Clave InChI: LRESCJAINPKJTO-UHFFFAOYSA-N

Descripción

Descripción general

1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [EMIM][N(Tf)₂] is a room temperature ionic liquid (RTIL). ([EMIM][N(Tf)₂]) as a non-aqueous solvent, is advantageous over traditional aprotic polar organic solvents in electrochemical investigation of electroactive species since it has low vapor pressure, high thermal stability, good conductivity and a wide electrochemical window. [EMIM][N(Tf)₂] shows good solubility in CO₂.

Aplicación

[EMIM][N(Tf)₂] may be used as a green solvent for the synthesis of zinc oxide (ZnO) nanoparticles under microwave conditions. It is useful in reactions which need a solvent with high CO₂ solubility.

Forma física

fluorinated, hydrophobic ionic liquid

Otras notas

Enantioselective reactions in ionic liquids

Información legal

Product protected by U.S. Patent 5,827,602 assigned to Covalent Associates, Inc. Woburn, Ma, USA

Información de seguridad

• Pictogramas: GHS06
• Palabra de señalización: Danger
• Frases de peligro: H301
• Consejos de prudencia: P264 - P270 - P301 + P310 - P405 - P501
• Clasificaciones de peligro: Acute Tox. 3 Oral
• Código de clase de almacenamiento: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Clase de riesgo para el agua (WGK): WGK 1
• Equipo de protección personal: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter