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Key Documents

8.04608

Sigma-Aldrich

Hydrazinium hydroxide

(about 100% N₂H₅OH) for synthesis

Sinónimos:

Hydrazinium hydroxide, Hydrazine hydrate

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About This Item

Fórmula empírica (notación de Hill):
H4N2 · xH2O
Número de CAS:
Peso molecular:
32.05 (anhydrous basis)
MDL number:
UNSPSC Code:
12352305
EC Index Number:
206-114-9
NACRES:
NA.22

vapor pressure

20 hPa ( 20 °C)

Quality Level

form

liquid

autoignition temp.

280 °C

potency

169 mg/kg LD50, oral (Rat)

expl. lim.

3.4-99 % (v/v)

pH

10-11 (20 °C, 10 g/L in H2O)

bp

120.5 °C/1013 hPa

mp

-51.7 °C

density

1.03 g/cm3 at 20 °C

storage temp.

15-25°C

InChI

1S/H4N2.H2O/c1-2;/h1-2H2;1H2

InChI key

IKDUDTNKRLTJSI-UHFFFAOYSA-N

Application

Hydrazinium hydroxide (N2H4.H2O) can be used as a reducing agent to synthesize:
  • Magnetic nickel nanoparticles by polyol process using nickel acetate as a precursor.
  • Cu@Cu2O core-shell nanoparticles via a chemical reduction method using CuSO4.5H2O as a precursor.

It can also be used as a reactant to prepare:
2H-indazolo[2,1-b]phthalazine-1,6,11(13H)-trione derivatives by Ce(SO4)2·4H2O catalyzed condensation reaction with phthalic anhydride, aromatic aldehydes, and dimedone.

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - Skin Sens. 1

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

100.4 °F - closed cup - (anhydrous substance)

flash_point_c

38 °C - closed cup - (anhydrous substance)


Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Visite la Librería de documentos

Synthesis and characterization of ferromagnetic nickel nanoparticles
Altincekic, TG, et al.
Journal of Superconductivity and Novel Magnetism, 25(8), 2771-2775 (2012)
A rapid, one-pot, four-component route to 2H-indazolo [2, 1-b] phthalazine-triones
Mosaddegh E and Hassankhani A
Tetrahedron Letters, 52(4), 488-490 (2011)
Synthesis and characterization of Cu@ Cu2O core shell nanoparticles prepared in seaweed Kappaphycus alvarezii Media
Khanehzaei H, et al.
International Journal of Electrochemical Science, 9, 8189-8198 (2014)

Protocolos

Fmoc resin cleavage and deprotection are crucial steps for peptide synthesis, yielding the desired peptide after resin detachment.

Fmoc resin cleavage and deprotection are crucial steps for peptide synthesis, yielding the desired peptide after resin detachment.

Fmoc resin cleavage and deprotection are crucial steps for peptide synthesis, yielding the desired peptide after resin detachment.

Fmoc resin cleavage and deprotection are crucial steps for peptide synthesis, yielding the desired peptide after resin detachment.

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