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Key Documents

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P29006

Sigma-Aldrich

Phenylphosphonic acid

98%

Sinónimos:

Benzene phosphonic acid

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About This Item

Fórmula lineal:
C6H5P(O)(OH)2
Número de CAS:
1571-33-1
Peso molecular:
158.09
Beilstein/REAXYS Number:
2245168
EC Number:
216-388-1
MDL number:
MFCD00002136
UNSPSC Code:
12352300
PubChem Substance ID:
24898371
NACRES:
NA.23

Quality Level

200

assay

98%

form

crystals

mp

162-164 °C (lit.)

SMILES string

OP(O)(=O)c1ccccc1

InChI

1S/C6H7O3P/c7-10(8,9)6-4-2-1-3-5-6/h1-5H,(H2,7,8,9)

InChI key

QLZHNIAADXEJJP-UHFFFAOYSA-N

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Application

Additive used with Noyori's catalyst for oxidation of sulfides to sulfones.

Noyori Oxidation (Sodium Tungstate Dihydrate, Hydrogen Peroxide, Methyltri-n-octylammonium Hydrogen Sulfate, Phosphonic Acid)
Self assembled monolayers (SAMs)of phenylphosphonic acid may be used to make the interface between organic semiconductors and transparent conductive oxides. The acid may be used to functionalize titania particles. Additive used with Noyorι¢s catalyst for greener oxidation of sulfides to sulfones.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

hcodes

H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
MKCM8316
MKCM0595
MKCJ5393
MKBD2147V
MKBT8259V

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Justin L Ford et al.
Helicobacter, 12(6), 609-615 (2007-11-16)
Helicobacter pylori can utilize phenylphosphonate as a sole source of phosphorus, and it is able to transport the phosphonate N-phosphonoacetyl-L-aspartate. However, H. pylori does not have any genes homologous to those of the known pathways for phosphonate degradation in bacteria
T Q Duong et al.
Magnetic resonance in medicine, 45(5), 801-810 (2001-04-27)
The apparent diffusion coefficients (ADCs) of a series of markers concentrated in the extracellular space of normal rat brain were measured to evaluate, by inference, the ADC of water in the extracellular space. The markers (mannitol, phenylphosphonate, and polyethylene glycols)
Important reaction parameters in the synthesis of phenylphosphonic acid functionalized titania particles by reactive milling.
Betke A and Kickelbick G
New. J. Chem., 38(3), 1264-1270 (2014)
Zhaohui Cui et al.
Langmuir : the ACS journal of surfaces and colloids, 26(1), 179-182 (2009-08-04)
The in situ crystallization technique has been utilized to fabricate zirconium phenylphosphonate (ZrPP) films with their hexagonal crystallite perpendicular to the copper substrate. The micro/nano roughness surface structure, as well as the intrinsic hydrophobic characteristic of the surface functional groups
Jannie P Wijnen et al.
PloS one, 9(7), e102256-e102256 (2014-07-19)
To assess the ability of a polarization transfer (PT) magnetic resonance spectroscopy (MRS) technique to improve the detection of the individual phospholipid metabolites phosphocholine (PC), phosphoethanolamine (PE), glycerophosphocholine (GPC), and glycerophosphoethanolamine (GPE) in vivo in breast tumor xenografts. The adiabatic
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