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Merck

75992

Sigma-Aldrich

Palladium on activated charcoal

greener alternative

5% Pd basis

Sinónimos:

Pd/C

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About This Item

Fórmula lineal:
Pd
MDL number:
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
NACRES:
NA.22

Quality Level

form

powder

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

greener alternative product characteristics

Designing Safer Chemicals
Catalysis
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sustainability

Greener Alternative Product

concentration

5% Pd

greener alternative category

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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Application

Palladium on activated charcoal (Pd/C) is a catalyst used in hydrogenation of alkenes, alkynes, ketones, nitriles, imines, nitro groups, aromatic and heteroaromatic systems. Pd/C also catalyzes phosphination of aryl bromides and triflates with triphenylphines to yield aryl phosphines.
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pictograms

Flame

signalword

Danger

hcodes

Hazard Classifications

Flam. Sol. 1

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 3

ppe

Eyeshields, Gloves, type N95 (US)


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Visite la Librería de documentos

Examination of the aromatic amination catalyzed by palladium on charcoal.
Komaromi, Anna and Novak, Zoltan
Advanced Synthesis & Catalysis, 352(9), 1523-1532 (2010)
Palladium on Carbon.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Alvise Perosa et al.
Chemosphere, 173, 535-541 (2017-02-01)
We describe a chemical technology for the reductive catalytic multiphase hydrodechlorination (HDC) of chlorinated aromatics to greatly reduce their toxicity and aid the disposal of such species. The system requires no solvent and the catalyst displays a high recycling efficiency.
Synthesis of aryl phosphines by phosphination with triphenylphosphine catalyzed by palladium on charcoal.
Lai, Chi Wai et al.
Tetrahedron Letters, 42(29), 4883-4885 (2001)
Sonogashira coupling of aryl halides catalyzed by palladium on charcoal.
Novak, Zoltan et al.
The Journal of Organic Chemistry, 68(8), 3327-3329 (2003)

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