718114

Manganese(II) chloride bis(lithium chloride) complex solution

0.5 M in THF, density: 0.956 g/mL at 25 °C

• Sinónimos: Lithium tetrachloromanganate(II) solution, Lithium chloromanganate(II), Lithium manganese chloride, Manganese(II) chloride bis(lithium chloride) complex solution
• Fórmula lineal: Li₂MnCl₄
• Número de CAS: 57384-24-4
• Peso molecular: 210.63
• MDL number: MFCD00192059
• UNSPSC Code: 12161600
• PubChem Substance ID: 329763551
• NACRES: NA.22

Propiedades

• form: liquid
• Quality Level: 100
• reaction suitability: core: manganese; reagent type: catalyst
• concentration: 0.5 M in THF
• density: 0.956 g/mL at 25 °C
• SMILES string: [Li+].[Li+].Cl[Mn--](Cl)(Cl)Cl
• InChI: 1S/4ClH.2Li.Mn/h4*1H;;;/q;;;;2*+1;+2/p-4
• InChI key: VJOUQNFWQPCDPE-UHFFFAOYSA-J

Descripción

Application

Catalyst for homocoupling of Grignard reagents using atmospheric oxygen as an oxidant

Reactant for:

• Transmetalation reactions
• Nickel-imidazolium carbene-catalyzed coupling reactions

Reagent for the preparation of Rieke manganese

Información de seguridad

• pictograms: GHS02,GHS08,GHS07
• signalword: Danger
• hcodes: H225,H302,H315,H319,H335,H351
• pcodes: P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• supp_hazards: EUH019
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 1.4 °F - closed cup
• flash_point_c: -17.0 °C - closed cup